Coating compositions

ABSTRACT

Various embodiments according to the present disclosure provide a coating composition. The coating composition includes a carrier. The coating composition further includes a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 50 wt %, relative to the total weight of the composition.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 62/858,174 entitled “COATING COMPOSITIONS,” filed Jun. 6, 2019, the disclosure of which is incorporated herein in its entirety by reference.

BACKGROUND

Fragrances can include fragrance components that can be classified, in part, by their volatility. Accordingly, these fragrance components may be referred to as a high-, middle-, or low-volatility fragrance components. Different fragrances may be dominated by any one or more of these components such that the fragrance may be associated with different perceptions by a user.

SUMMARY OF THE DISCLOSURE

Various embodiments according to the present disclosure provide a coating composition. The coating composition includes a carrier. The coating composition further includes a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Various embodiments according to the present disclosure provide a multi-component fragrance composition. The multi-component fragrance composition includes a coating composition. The coating composition includes a carrier. The coating composition further includes a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition. The multi-component fragrance composition further includes a fragrance composition in contact with the coating composition.

Various embodiments according to the present disclosure further provide a method of using a coating composition. The coating composition includes a carrier. The coating composition further includes a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition. The method includes contacting a fragrance composition with the coating composition.

BRIEF DESCRIPTION OF THE FIGURES

The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present document.

FIG. 1 is a set of graphs identifying the most frequent comments by experts comparing a sample with coating vs. control (without coating) at t=3 h, in accordance with various embodiments.

DETAILED DESCRIPTION

Reference will now be made in detail to certain embodiments of the disclosed subject matter. While the disclosed subject matter will be described in conjunction with the enumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.

As used herein, articles such as “a” and “an” when used in a claim, are understood to mean one or more of what is claimed or described.

As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.

As used herein, the term “body splash” means a body care formulation that is applied to the body. Typically, the body splash is applied to the body after bathing and provides a subtle hint of scent to the body. Body splashes are commonly used by consumers who prefer less strong fragrance compositions. A body splash may comprise an ethanol-free composition according to the present invention which comprises from 0.2-8 wt %, relative to the total weight of the composition, of a fragrance component. The body splash may further comprise alkyl polyglucosides as non-ionic surfactants.

As used herein, the term “body spray” means a formulation comprising fragrance materials intended to be applied to the body to prevent or mask body odor caused by the bacterial breakdown of perspiration on the body (e.g., armpits, feet, and other areas of the body). The body spray may also provide a fragrance expression to the consumers. Typically, body spray compositions are applied as an aerosol spray in an effective amount on the skin of a consumer.

As used herein, the term “composition” includes a fine fragrance composition intended for application to a body surface, such as for example, skin or hair, e.g., to impart a pleasant odor thereto, or cover a malodour thereof. They are generally in the form of perfume concentrates, perfumes, eau de parfums, eau de toilettes, aftershaves, or colognes. The fine fragrance compositions may be an ethanol-based composition. The term “composition” may also include a cosmetic composition, which comprises a fragrance material for the purposes of delivering a pleasant smell to drive consumer acceptance of the cosmetic composition. The term “composition” may also include body splashes or body sprays. The term “composition” may also include cleaning compositions, such as fabric care composition or home care compositions, including air care compositions (e.g., air fresheners), for use on clothing or other substrates such as hard surfaces (e.g., dishes, floors, countertops). Additional non-limiting examples of “composition” may also include facial or body powder, deodorant, foundation, body/facial oil, mousse, creams (e.g., cold creams), waxes, sunscreens and blocks, bath and shower gels, lip balms, self-tanning compositions, masks and patches.

As used herein, the term “consumer” means both the user of the composition and the observer nearby or around the user.

As used herein, the term “fragrance material” and “fragrance materials” relates to a perfume raw material (“PRM”), or a mixture of perfume raw materials (“PRMs”), that are used to impart an overall pleasant odor or fragrance profile to a composition. “Fragrance materials” can encompass any suitable perfume raw materials for fragrance uses, including materials such as, for example, alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpene hydrocarbons, nitrogenous or sulfurous heterocyclic compounds and essential oils. However, naturally occurring plant and animal oils and exudates comprising complex mixtures of various chemical components are also known for use as “fragrance materials”. The individual perfume raw materials which comprise a known natural oil can be found by reference to Journals commonly used by those skilled in the art such as “Perfume and Flavourist” or “Journal of Essential Oil Research”, or listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, N.J., USA and more recently re-published by Allured Publishing Corporation Illinois (1994). Additionally, some perfume raw materials are supplied by the fragrance houses (Firmenich, International Flavors & Fragrances, Givaudan, Symrise) as mixtures in the form of proprietary specialty accords. Non-limiting examples of the fragrance materials useful herein include pro-fragrances such as acetal pro-fragrances, ketal pro-fragrances, ester pro-fragrances, hydrolyzable inorganic-organic pro-fragrances, and mixtures thereof. The fragrance materials may be released from the pro-fragrances in a number of ways. For example, the fragrance may be released as a result of simple hydrolysis, or by a shift in an equilibrium reaction, or by a pH-change, or by enzymatic release.

As used herein, the term “fragrance profile” means the description of how the fragrance is perceived by the human nose at any moment in time. The fragrance profile may change over time. It is a result of the combination of the low, moderate and high volatile fragrance materials, if present, of a fragrance. A fragrance profile is composed of 2 characteristics: ‘intensity’ and ‘character’. The ‘intensity’ relates to the perceived strength whilst ‘character’ refers to the odor impression or quality of the perfume, e.g., fruity, floral, woody, etc.

As used herein, the terms “modulator”, and “fragrance modulator” are used interchangeably to designate an agent having the capacity to affect the fragrance profile, such as for example, by impacting the fragrance materials' evaporation rate. The modulator may mediate its effect by lowering the vapor pressure of the fragrance materials and increasing their adherence to the substrate (skin and/or hair) thus ensuring a less harsh impression of the overdosed fragrance.

By incorporating the modulator, it is desired that the fragrance profile, preferably the fragrance components composition attributable to the moderate and low volatile fragrance materials, alone or individually, of the composition can be perceived by a panel of experts or professional evaluators or individual experts or professional evaluators, without the perceived harshness of overdosing (e.g., greater than about 30 wt % of the composition) of the low and moderate fragrance materials is mitigated or absent, as compared to the same perception in the absence of the modulator. Suitable examples of the modulator are provided herein below. However, as discovered by the inventors, simply adding a primer containing modulators to a traditionally constructed fragrance composition (e.g., classical fragrance pyramid construction without overdose) that is commercially available in the market will enhance the perception of medium and high volatile materials and preserve them overtime. It is necessary that fragrance construction has a predominantly green, fruity, floral and citrus character to achieve best results. Nonetheless desired character change is achieved with any commercial fragrance as described by experts or professional evaluators or individual experts or professional evaluators experience. Without intending to be limited to any theory, the inventors believe that the modulator increases solubility of at least one hydrophobic perfume raw material fragrance materials relative to a fragrance composition lacking the modulator. This can be accomplished via van der walls and hydrogen bonding between the modulator and the hydrophobic perfume raw materials.

As used herein, the term “substantially non-odorous” means an agent that does not impart an odor of its own when added into a composition of the present invention. For example, a “substantially non-odorous fragrance modulator” does not impart a new odor that alters the character of the fragrance profile of the composition to which it is added. The term “substantially non-odorous” also encompasses an agent that may impart a minimal or slight odor of its own when added into a composition of the present invention. However, the odor imparted by the “substantially non-odorous fragrance modulator” is generally undetectable or tends to not substantively alter the character of the fragrance profile of the composition to which it is added initially or preferably over time. Furthermore, the term “substantially non-odorous” also includes materials that are perceivable only by a minority of people or those materials deemed “anosmic” to the majority of people. Furthermore, the term “substantially non-odorous” also includes materials that may, from particular suppliers, contain an odor due to impurities, such as when the materials contain the impurities at not more than about 5 wt %, preferably not more than 1 wt %, often even not more than 1 part per million (ppm). These impurities maybe removed by purification techniques known in the art as required to make them suitable for use in fragrance compositions of the present invention.

As used herein, the term “vapor pressure” means the partial pressure in air at a defined temperature (e.g., 25° C.) and standard atmospheric pressure (760 mmHg) for a given chemical species. It defines a chemical species' desire to be in the gas phase rather than the liquid or solid state. The higher the vapor pressure the greater the proportion of the material that will, at equilibrium, be found in a closed headspace. It is also related to the rate of evaporation of a fragrance material which is defined in an open environment where material is leaving the system. The vapor pressure is determined according to the reference program Advanced Chemistry Development (ACD/Labs) Software Version 14.02, or preferably the latest version update).

It is understood that the test methods that are disclosed in the Test Methods Section of the present application must be used to determine the respective values of the parameters of Applicants' inventions as described and claimed herein.

In all embodiments of the present invention, all percentages are by weight of the total composition, as evident by the context, unless specifically stated otherwise. All ratios are weight ratios, unless specifically stated otherwise, and all measurements are made at 25° C., unless otherwise designated.

Throughout this document, values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.

In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. The statement “at least one of A and B” has the same meaning as “A, B, or A and B.” In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that particular section.

In the methods described herein, the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.

The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range, and includes the exact stated value or range.

The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more, or 100%.

The term “organic group” as used herein refers to any carbon-containing functional group. Examples can include an oxygen-containing group such as an alkoxy group, aryloxy group, aralkyloxy group, oxo(carbonyl) group; a carboxyl group including a carboxylic acid, carboxylate, and a carboxylate ester; a sulfur-containing group such as an alkyl and aryl sulfide group; and other heteroatom-containing groups. Non-limiting examples of organic groups include OR, OOR, OC(O)N(R)₂, CN, CF₃, OCF₃, R, C(O), methylenedioxy, ethylenedioxy, N(R)₂, SR, SOR, SO₂R, SO₂N(R)₂, SOR, C(O)R, C(O)C(O)R, C(O)CH₂C(O)R, C(S)R, C(O)OR, OC(O)R, C(O)N(R)₂, OC(O)N(R)₂, C(S)N(R)₂, (CH₂)₀₋₂N(R)C(O)R, (CH₂)₀₋₂N(R)N(R)₂, N(R)N(R)C(O)R, N(R)N(R)C(O)OR, N(R)N(R)CON(R)₂, N(R)SO₂R, N(R)SO₂N(R)₂, N(R)C(O)OR, N(R)C(O)R, N(R)C(S)R, N(R)C(O)N(R)₂, N(R)C(S)N(R)₂, N(COR)COR, N(OR)R, C(═NH)N(R)₂, C(O)N(OR)R, C(═NOR)R, and substituted or unsubstituted (C₁-C₁₀₀)hydrocarbyl, wherein R can be hydrogen (in examples that include other carbon atoms) or a carbon-based moiety, and wherein the carbon-based moiety can be substituted or unsubstituted.

The term “substituted” as used herein in conjunction with a molecule or an organic group as defined herein refers to the state in which one or more hydrogen atoms contained therein are replaced by one or more non-hydrogen atoms. The term “functional group” or “substituent” as used herein refers to a group that can be or is substituted onto a molecule or onto an organic group. Examples of substituents or functional groups include, but are not limited to, a halogen (e.g., F, Cl, Br, and I); an oxygen atom in groups such as hydroxy groups, alkoxy groups, aryloxy groups, aralkyloxy groups, oxo(carbonyl) groups, carboxyl groups including carboxylic acids, carboxylates, and carboxylate esters; a sulfur atom in groups such as thiol groups, alkyl and aryl sulfide groups, sulfoxide groups, sulfone groups, sulfonyl groups, and sulfonamide groups; a nitrogen atom in groups such as amines, hydroxyamines, nitriles, nitro groups, N-oxides, hydrazides, azides, and enamines; and other heteroatoms in various other groups. Non-limiting examples of substituents that can be bonded to a substituted carbon (or other) atom include F, Cl, Br, I, OR, OC(O)N(R)₂, CN, NO, NO₂, ONO₂, azido, CF₃, OCF₃, R, O (oxo), S (thiono), C(O), S(O), methylenedioxy, ethylenedioxy, N(R)₂, SR, SOR, SO₂R, SO₂N(R)₂, SO₃R, C(O)R, C(O)C(O)R, C(O)CH₂C(O)R, C(S)R, C(O)OR, OC(O)R, C(O)N(R)₂, OC(O)N(R)₂, C(S)N(R)₂, (CH₂)₀₋₂N(R)C(O)R, (CH₂)₀₋₂N(R)N(R)₂, N(R)N(R)C(O)R, N(R)N(R)C(O)OR, N(R)N(R)CON(R)₂, N(R)SO₂R, N(R)SO₂N(R)₂, N(R)C(O)OR, N(R)C(O)R, N(R)C(S)R, N(R)C(O)N(R)₂, N(R)C(S)N(R)₂, N(COR)COR, N(OR)R, C(═NH)N(R)₂, C(O)N(OR)R, and C(═NOR)R, wherein R can be hydrogen or a carbon-based moiety; for example, R can be hydrogen, (C₁-C₁₀₀)hydrocarbyl, alkyl, acyl, cycloalkyl, aryl, aralkyl, heterocyclyl, heteroaryl, or heteroarylalkyl; or wherein two R groups bonded to a nitrogen atom or to adjacent nitrogen atoms can together with the nitrogen atom or atoms form a heterocyclyl.

The term “alkyl” as used herein refers to straight chain and branched alkyl groups and cycloalkyl groups having from 1 to 40 carbon atoms, 1 to about 20 carbon atoms, 1 to 12 carbons or, in some embodiments, from 1 to 8 carbon atoms. Examples of straight chain alkyl groups include those with from 1 to 8 carbon atoms such as methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, and n-octyl groups. Examples of branched alkyl groups include, but are not limited to, isopropyl, iso-butyl, sec-butyl, t-butyl, neopentyl, isopentyl, and 2,2-dimethylpropyl groups. As used herein, the term “alkyl” encompasses n-alkyl, isoalkyl, and anteisoalkyl groups as well as other branched chain forms of alkyl. Representative substituted alkyl groups can be substituted one or more times with any of the groups listed herein, for example, amino, hydroxy, cyano, carboxy, nitro, thio, alkoxy, and halogen groups.

The term “alkenyl” as used herein refers to straight and branched chain and cyclic alkyl groups as defined herein, except that at least one double bond exists between two carbon atoms. Thus, alkenyl groups have from 2 to 40 carbon atoms, or 2 to about 20 carbon atoms, or 2 to 12 carbon atoms or, in some embodiments, from 2 to 8 carbon atoms. Examples include, but are not limited to vinyl, —CH═CH(CH₃), —CH═C(CH₃)₂, —C(CH₃)═CH₂, —C(CH₃)═CH(CH₃), —C(CH₂CH₃)═CH₂, cyclohexenyl, cyclopentenyl, cyclohexadienyl, butadienyl, pentadienyl, and hexadienyl among others.

The term “alkynyl” as used herein refers to straight and branched chain alkyl groups, except that at least one triple bond exists between two carbon atoms. Thus, alkynyl groups have from 2 to 40 carbon atoms, 2 to about 20 carbon atoms, or from 2 to 12 carbons or, in some embodiments, from 2 to 8 carbon atoms. Examples include, but are not limited to —C≡CH, —C≡C(CH₃), —C≡C(CH₂CH₃), —CH₂C≡CH, —CH₂C≡C(CH₃), and —CH₂C≡C(CH₂CH₃) among others.

The term “acyl” as used herein refers to a group containing a carbonyl moiety wherein the group is bonded via the carbonyl carbon atom. The carbonyl carbon atom is bonded to a hydrogen forming a “formyl” group or is bonded to another carbon atom, which can be part of an alkyl, aryl, aralkyl cycloalkyl, cycloalkylalkyl, heterocyclyl, heterocyclylalkyl, heteroaryl, heteroarylalkyl group or the like. An acyl group can include 0 to about 12, 0 to about 20, or 0 to about 40 additional carbon atoms bonded to the carbonyl group. An acyl group can include double or triple bonds within the meaning herein. An acryloyl group is an example of an acyl group. An acyl group can also include heteroatoms within the meaning herein. A nicotinoyl group (pyridyl-3-carbonyl) is an example of an acyl group within the meaning herein. Other examples include acetyl, benzoyl, phenylacetyl, pyridylacetyl, cinnamoyl, and acryloyl groups and the like. When the group containing the carbon atom that is bonded to the carbonyl carbon atom contains a halogen, the group is termed a “haloacyl” group. An example is a trifluoroacetyl group.

The term “cycloalkyl” as used herein refers to cyclic alkyl groups such as, but not limited to, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl groups. In some embodiments, the cycloalkyl group can have 3 to about 8-12 ring members, whereas in other embodiments the number of ring carbon atoms range from 3 to 4, 5, 6, or 7. Cycloalkyl groups further include polycyclic cycloalkyl groups such as, but not limited to, norbornyl, adamantyl, bornyl, camphenyl, isocamphenyl, and carenyl groups, and fused rings such as, but not limited to, decalinyl, and the like. Cycloalkyl groups also include rings that are substituted with straight or branched chain alkyl groups as defined herein. Representative substituted cycloalkyl groups can be mono-substituted or substituted more than once, such as, but not limited to, 2,2-, 2,3-, 2,4-2,5- or 2,6-disubstituted cyclohexyl groups or mono-, di- or tri-substituted norbornyl or cycloheptyl groups, which can be substituted with, for example, amino, hydroxy, cyano, carboxy, nitro, thio, alkoxy, and halogen groups. The term “cycloalkenyl” alone or in combination denotes a cyclic alkenyl group.

The term “aryl” as used herein refers to cyclic aromatic hydrocarbon groups that do not contain heteroatoms in the ring. Thus aryl groups include, but are not limited to, phenyl, azulenyl, heptalenyl, biphenyl, indacenyl, fluorenyl, phenanthrenyl, triphenylenyl, pyrenyl, naphthacenyl, chrysenyl, biphenylenyl, anthracenyl, and naphthyl groups. In some embodiments, aryl groups contain about 6 to about 14 carbons in the ring portions of the groups. Aryl groups can be unsubstituted or substituted, as defined herein. Representative substituted aryl groups can be mono-substituted or substituted more than once, such as, but not limited to, a phenyl group substituted at any one or more of 2-, 3-, 4-, 5-, or 6-positions of the phenyl ring, or a naphthyl group substituted at any one or more of 2- to 8-positions thereof.

The term “aralkyl” as used herein refers to alkyl groups as defined herein in which a hydrogen or carbon bond of an alkyl group is replaced with a bond to an aryl group as defined herein. Representative aralkyl groups include benzyl and phenylethyl groups and fused (cycloalkylaryl)alkyl groups such as 4-ethyl-indanyl. Aralkenyl groups are alkenyl groups as defined herein in which a hydrogen or carbon bond of an alkyl group is replaced with a bond to an aryl group as defined herein.

The term “heterocyclyl” as used herein refers to aromatic and non-aromatic ring compounds containing three or more ring members, of which one or more is a heteroatom such as, but not limited to, N, O, and S.

The term “heteroaryl” as used herein refers to aromatic ring compounds containing 5 or more ring members, of which, one or more is a heteroatom such as, but not limited to, N, O, and S; for instance, heteroaryl rings can have 5 to about 8-12 ring members. A heteroaryl group is a variety of a heterocyclyl group that possesses an aromatic electronic structure.

As used herein, the term “hydrocarbyl” refers to a functional group derived from a straight chain, branched, or cyclic hydrocarbon, and can be alkyl, alkenyl, alkynyl, aryl, cycloalkyl, acyl, or any combination thereof. Hydrocarbyl groups can be shown as (C_(a)-C_(b))hydrocarbyl, wherein a and b are integers and mean having any of a to b number of carbon atoms. For example, (C₁-C₄)hydrocarbyl means the hydrocarbyl group can be methyl (C₁), ethyl (C₂), propyl (C₃), or butyl (C₄), and (C₀-C_(b))hydrocarbyl means in certain embodiments there is no hydrocarbyl group.

Compositions

Compositions described herein can relate to a coating composition such as a primer or topcoat that includes a substantially non-odorous fragrance modulator. The coating composition can further include a carrier in which the substantially non-odorous fragrance modulator is dispersed.

Fragrance Modulators

The coating composition comprises at least one substantially non-odorous fragrance modulator as described herein below. Suitable examples of the substantially non-odorous fragrance modulators are provided in Table 1 below.

The substantially non-odorous fragrance modulator can be present in an amount of from about 0.1 wt % to about 50 wt % relative to the total weight of the coating composition or the composition, about 0.5 wt % to about 40 wt %, about 2.5 wt % to about 15 wt %, or less than, equal to, or greater than about 0.1 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.5, 27.5, 28, 28.5, 29, 29.5, 30, 30.5, 31, 31.5, 32, 32.5, 33, 33.5, 34, 34.5, 35, 35.5, 36, 36.5, 37, 37.5, 38, 38.5, 39, 39.5, 40, 40.5, 41, 41.5, 42, 42.5, 43, 43.5, 44, 44.5, 45, 45.5, 46, 46.5, 47, 47.5, 48, 48.5, 49, 49.5, 50 wt %. If there are more than one substantially non-odorous fragrance modulators, then the ranges provided herein above cover the total of all of the substantially non-odorous fragrance modulators in the composition. According to various embodiments, the modulator can be present exclusively in a primer as opposed to being in a fragrance composition.

The substantially non-odorous fragrance modulator can be a liquid at temperatures lower than 100° C., such as at ambient temperature. The substantially non-odorous fragrance modulators may be fully miscible with a fragrance material(s) to form a single-phase liquid. However, if the fragrance materials are not entirely miscible, or are immiscible, then co-solvents (e.g., dipropylene glycol (DPG), triethyl citrate, or others well known to those skilled in the art) can be added to aid in the solubility of the fragrance materials.

The coating can be used in conjunction with a fragrance composition. For example, the fragrance composition can be applied to the coating and the substantially non-odorous fragrance modulator can permeate to the fragrance component. The coating can be left to dry or be a liquid when a fragrance component is brought into contact with the coating. The effect of the substantially non-odorous fragrance modulator on the fragrance profile, particularly the characters of the fragrance profile which is attributable to the medium and high volatile fragrance materials, can be improved. By “improved” it is meant that the fragrance profile of the composition, particularly the components contributed by at least one of the medium and high volatile fragrance materials, can be perceived by the panel of experts or professional evaluators or individual experts or professional evaluators at later time points such as, for example, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 6 hours, 7 hours, 8 hours, 10 hours, and possibly all the way up to 24 hrs after application as compared to controls, e.g., lacking any of the disclosed non-odorous fragrance modulators such as Glucam.

Suitable examples of non-odorous modulators can include methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof. Further examples can include from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl/capryl glucoside, undecyl glucoside, and mixtures thereof. In some examples, the composition can be substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof, although the composition can optionally include these.

Further examples of non-odorous modulators include:

a compound of formula (I):

wherein:

R¹ is hydrogen, alkyl, alkenyl or alkynyl;

R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)O]_(w)R⁹, wherein w is from 1 to 10, preferably 2 to 9;

R³ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]yR⁹, wherein y is

from 1 to 10 or 2 to 9;

R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;

R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶OR⁹, —R⁶O [R⁶R⁷(R⁸)O]zR⁹,

wherein z is from 1 to 10, preferably 2 to 9;

each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and

each R⁸ and R⁹ is independently selected from hydrogen or alkyl, a compound of formula (II):

wherein:

R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)alkynyl;

each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;

each R¹² is independently selected from hydrogen, (C₂-C₂))alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;

each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;

each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and

R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀) alkynyl;

wherein t is 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and     -   is a saturated or unsaturated carbon-carbon bond:

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   R^(1b) is hydrogen or methyl; and         R^(2b) is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)—(OR^(1c))_(n)   (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from         6 to 9, and m is an integer from 1 to 4;     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)   (VII).

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is an integer from 1 to 5;     -   z is an integer from 1 to 5; and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8,     -   and d is an integer from 1 to 3;     -   e is an integer from 2 to 4;     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4;     -   h is an integer from 2 to 5;     -   and R^(1f) is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)COOR^(3i)   (X).

wherein:

-   -   R^(1g) is selected from the group consisting of: (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)   (XII).

wherein:

-   -   R^(1i) is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and

Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H   (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and         their mixtures; Tricyclodecane Amide derivatives selected from         the group consisting of:     -   the compounds of formula (XIV):

-   -   wherein:         -   X is selected from:

t is 1 to 8;

-   -   Y is hydrogen, or a halogen; and     -   each R^(1j) is independently selected from a hydrogen, or C₁-C₄         alkyl;         the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈ alkyl, cycloalkyl or cycloheteroalkyl with the         proviso that both R^(2e) groups are not hydrogen; and         mixtures of the compounds of formulae (XII) and (XIII); and         mixtures thereof.

Tables 1(a) and 1(b) provide lists of suitable non-odorous fragrance modulators.

TABLE 1(a) Substantially Non-Odorous Fragrance Modulators No. Group Chemical Name CAS Number Supplier 1. (a) PPG-10 Methyl Glucose Ether 61849-72-7 Lubrizol 2. PPG-20 Methyl Glucose Ether ¹ 61849-72-7 3. Ethoxylated Methyl Glucose 68239-42-9 Ether ² 4. Caprylyl/Capryl Glucoside ³ 68515-73-1 BASF 5. Undecyl Glucoside ^(3a) — SEPPIC (France) 6. (b) Isocetyl Alcohol ⁴ 36653-82-4 Ashland Speciality Ingredients 7. (c) PPG-3 Myristyl Ether ⁵ — Evonik 8. Neopentyl Glycol 28510-23-8 Lubrizol Diethylhexanoate ⁶ 9. (d) Sucrose Laurate 25339-99-5 Alfa Chemicals Ltd. (UK) 10. Sucrose dilaurate 25915-57-5 Alfa Chemicals Ltd. (UK) 11. Sucrose Myristate 27216-47-3 Mitsubishi Chemicals 12. Sucrose Palmitate 26446-38-8 Alfa Chemicals Ltd. (UK) 13. Sucrose Stearate 25168-73-4 14. Sucrose Distearate 27195-16-0 Mitsubishi Chemicals (JP) 15. Sucrose Tristearate 27923063-3 Mitsubishi Chemicals (JP) 16. (e) (E)-1-(2,2,6- — Takasago (Japan) trimethylcyclohexyl)oct-1-en-3-one ⁸ 17. (f) 2-(1-menthoxy)ethane-1-ol ⁹ — Takasago (Japan) 18. 1-(1-menthoxy)propane-2-ol ⁹ — 19. 3-(1-menthoxy)propane-1-ol ⁹ — 20. 3-(1-menthoxy)propane-1,2- — diol ⁹ 21. 2-methyl-3-(1- — menthoxy)propane-1,2-diol ⁹ 22. 4-(1-menthoxy) butane-1-ol ⁹ — 23. (g) 1,1,4,4-tetramethy1-6-acetyl-7- Givaudan (Switzerland) formyl-1,2,3,4- — tetrahydronaphthalene ¹⁰ 24. 1,1,2,4,4-pentamethyl-6-acetyl- — 7-formyl-1,2,3,4- tetrahydronaphthalene ¹⁰ 25. (h) Hyaluronic acid disaccharide 9004-61-9 Sigma Aldrich (UK) sodium salt ¹¹ 26. Sodium Hyaluronate ¹¹ 9067-32-7 27. (i) Mono-o-(linalyl)-glucopyranose ¹² — Kanebo (Japan) 28. Di-o-(linalyl)-glucopyranose ¹² — 29. Tri-o-(linalyl)-glucopyranose ¹² — 30. Tretra-o-(linalyl)-glucopyranose ¹² — 31. Penta-o-(linayl)-glucopyranose ¹² — 32. Mono-o-(cis-3-hexenyl)- — glactopyranose ¹² 33. Di-o-(cis-3-hexenyl)- — glactopyranose ¹² 34. Tri-o-(cis-3-hexenyl)- — glactopyranose ¹² 35. Tetra-o-(cis-3-hexenyl)- — glactopyranose ¹² 36. Penta-o-(cis-3-hexenyl)- — glactopyranose ¹² 37. (j) Bis-O-(3,6-dioxadecanyl)- — glucopyranose ¹³ 38. Tris-O-(3,6-dioxadecanyl)- — glucopyranose ¹³ 39. Tetrakis-O-(3,6-dioxadecanyl)- — glucopyranose ¹³ 40. Pentakis-O-(3,6-dioxadecanyl)- — glucopyranose ¹³ 41. Bis-O-(3,6-dioxaoctanyl)- — galactopyranose ¹³ 42. Tris-O-(3,6-dioxaoctanyl)- — galactopyranose ¹³ 43. Tetrakis-O-(3,6-dioxaoctanyl)- — galactopyranose ¹³ 44. Pentakis-O-(3,6-dioxaoctanyl)- — galactopyranose ¹³ 45. Bis-O-(3,6-dioxaheptanyl)- — xylopyranose ¹³ 46. Tris-O-(3,6-dioxaheptanyl)- — xylopyranose ¹³ 47. Tetrakis-O-(3,6-dioxaheptanyl)- — xylopyranose ¹³ 48. Bis-O-(3,6-dioxadodecanyl)- — glucopyranose ¹³ 49. Tris-O-(3,6-dioxadodecanyl)- — glucopyranose ¹³ 50. Tetrakis-O-(3,6-dioxadodecanyl)- — glucopyranose ¹³ 51. Pentakis-O-(3,6-dioxadodecanyl)- — glucopyranose ¹³ 52. (k) Hydroquinone beta-D-glycoside ¹⁴ 497-76-7 Shiseido 53. (l) Propylene Glycol Propyl Ether 1569-01-3 Sigma Aldrich (UK) 54. Dicetyl Ether 4113-12-6 55. Propyglycerin-4 Ethers 25618-55-7 Solvay Chemicals 56. Isoceteth-5 69364-63-2 Nihon Emulsion 57. Isoceteth-7 69364-63-2 Company Ltd. 58. Isoceteth-10 69364-63-2 59. Isoceteth-12 69364-63-2 60. Isoceteth-15 69364-63-2 61. Isoceteth-20 69364-63-2 62. Isoceteth-25 69364-63-2 63. Isoceteth-30 69364-63-2 64. Disodium 68929-04-4 Rhodia Lauroamphodipropionate 65. Hexaethylene glycol 3055-96-7 Sigma Aldrich (UK) monododecyl ether ^(14b) 66. (m) Neopentyl Glycol 27841-07-2 Symrise (Germany) Diisononanoate ¹⁵ 67. Cetearyl Ethylhexnoate ¹⁶ 90411-68-0 68. (n) 2-ethylhexyloxypropanediol ¹⁷ 70455-33-9 Takasago (JP) 69. (o) Panthenol Ethyl Ether ¹⁸ 667-83-4 DSM Nutritional Products, Inc. (USA) 70. DL-Panthenol 16485-10-2 Roche Inc. (USA) 71. (p) Diisobutyl Adipate ¹⁹ 141-04-8 Sigma Aldrich (UK) 72. Diisoamyl Adipate ¹⁹ 6624-70-0 73. (q) PPG-11 Stearyl Ether ^(19a) 25231-21-4 Kao (JP) 74. (r) N-hexadecyl n-nonanoate ^(19b) 72934-15-7 Symrise (Germany) (e.g., cetyl nonanoate) 75. Noctadecyl n-nonanoate ^(19b) 107647-13-2 (e.g., stearyl nonanoate) 76. (s) methanone, (morphonyl) — Unilever (UK) tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 77. methanone, (piperidinyl) — tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 78. methanone, (pyrrolidinyl) — tricyclo[3.3.1.1^(3,7)]dec-1-yl ²⁰ 79. methanone, (azetidinyl) — tricyclo[3.3,1.1^(3,7)]dec-1-yl- ²⁰ 80. methanone, (hexahydroazepinyl) — tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 81. methanone, (4-cyano- — piperidinyl)tricyclo[3.3.1.1^(3,7)]dec- 1-yl- ²⁰ 82. methanone, 4-amido- — piperidinyl)tricyclo[3.3.1.1^(3,7)]dec- 1-yl- ²⁰ 83. methanone, — (Tricyclo[3.3.1.1^(3,7)]decanyl)-N- tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 84. methanone, — (decahydroisoquinolinyl)tri- cyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 85. methanone, — (decahydroisoquinolinyl)tri- cyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 86. methanone, — (decahydroquinolinyl)tri- cyclo[3.3.1.1^(3.7)]dec-1-yl- ²⁰ 87. methanone, (3,3-dimethyl-1- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 88. methanone, (2-methyl-1- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 89. methanone, (4-methyl-1- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 90. methanone, (3-methyl-1- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 91. methanone, (3,5-dimethyl-1- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 92. methanone, (4-methyl-4-ethy- — piperidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 93. methanone, (3,3-diethyl-1- — pyrrolidinyl)tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 94. methanone, (N,N-diisopropyl) — tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 95. methanone, (3,3- — dimethylbutylaminyl) tricyclo[3.3,1.1^(3,7)]dec-1-yl- ²⁰ 96. methanone, (2,2- — dimethylpropylaminyl) tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 97. methanone, (1,1-dimethy1-3,3- — dimethylbutylaminyl) tricyclo[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 98. methanone, (1,3-dimethyl- — butylaminyl) tricycle[3.3.1.1^(3,7)]dec-1-yl- ²⁰ 99. (t) Bis-methoxy PEG-13 PEG- 936645-35-1 PolymerExpert 438/PPG-110 SMDI Copolymer ²¹ S.A. (Pessac, France) 100. (u) propyl {4-[2-(diethylamino)-2- 61791-12-6 Sigma Aldrich (US) oxoethoxy]-3- methoxyphenyl}acetate ²² 101. (v) 3-((2-ethylhexyl)oxy)propane- 70445-33-9 — 1,2-diol ²³ 102. 3-((2-propylheptyl)oxy)propane- — — 1,2-diol ²³ 103. 1-amino-3-((2- 99509-00-9 — ethylhexyl)oxy)propan-2-ol ²³ ¹ available as GLUCAM ™ P-20. ² available as Glucam ™ E-20. ³ available as Plantacare ® 810 UP. ^(3a) available as Simulsol ® SL 11W. ⁴ available as CERAPHYL ® ICA. ⁵ available as Tegosoft ® APM. ⁶ available as Schercemol ™ NGDO. ⁷ disclosed in U.S. Pat. No. 6,737,396B2 (Firmenich), column 1, lines 43-47. ⁸ diclosed as compound 1'i in U.S. Pat. No. 6,440,400B1 (Takasago Int. Corp.), col. 5. ^(8a) diclosed in U.S. Pat. No. 4,313,855 (Dragoco Gerberding & Co. GmbH), col. 1, lines 12-13. ⁹ disclosed in U.S. Pat. No. 7,538,081B2 (Takasago Int. Corp.), column 7, lines 50-53. ¹⁰ disclosed in U.S. Pat. No. 6,147,049 (Givaudan Roure), col. 5, line 24, to col. 6, line 17. ¹¹ disclosed in PCT Publication No. WO85/04803 (Diagnostic), pg. 2, line 1 to pg. 4, line 2. ¹² disclosed in JP Patent No. 61-083114 (Kanebo). ¹³ disclosed in JP Patent No. 61-063612 (Kanebo). ¹⁴ disclosed in JP Patent No. 62-084010 (Shiseido). ^(14b) available as: Laureth-6. ¹⁵ disclosed in U.S. Pat. Publication No. 2011/0104089A1 (Symrise), para. [0001]. ¹⁶ available as PCL-Liquid ® 100. ¹⁷ disclosed in U.S. Pat. No. 7,196,052 (Takasago Int. Corp.), col. 4, lines 34-35. ¹⁸ disclosed in EP Patent Publication No. 616800A2 (Givaudan), pg. 2, lines 12-25. ¹⁹ disclosed in U.S. Pat. No. 4,110,626 (Shiseido), column 3, lines 54-56. ^(19a) disclosed in PCT Publication No. WO2014/155019 (LVMH). ^(19b) disclosed in U.S. Pat. No. 9,050,261 (Symrise). ²⁰ disclosed as compounds C1-C22 in WO2014/139952 (Unilever). ²¹ available as Expert Gel ® EG56. ²² available as Kolliphor ® EL. ²³ disclosed in U.S. Pat. No. 9,050,261 (Symrise).

Further examples of non-odorous fragrance modulator is selected from the group of materials disclosed in Table 1(b).

TABLE 1(b) Substantially Non-Odorous Fragrance Modulators Chemical or No. INCI Name Trade Name CAS Number Supplier 1. C12-14 Sec- Tergitol ® 68131-40-8 Sigma Aldrich (UK) Pareth-3 15-S-7 2. Poly(ethylene PPG-7- 9038-95-3 Sigma Aldrich (UK) glycol-ran- Buteth-10 propylene glycol) monobutyl ether 3. PPG-4-Ceteth-10 Nikkol PBC-33 37311-01-6 Chemical Navi 4. Deceth-4 Ethal DA-4 5703-94-6 Ethox Chemicals, Inc. 5. PPG-5-Ceteth-20 AEC PPG-5- 9087-53-0 A & E Connock Ceteth-20 (Perfumery & Cosmetics) Ltd. 6. C14-15 Pareth-7 Neodol 45-7 68951-67-7 Shell Chemical alcohol Company ethoxylate 7. Linear alcohol Bio-soft N25-7 68131-39-5 Stephan (C12-15) Pareth- Company (USA) 3ethoxylate, POE-7 8. Linear alcohol Bio-soft N23-6.5 66455-14-9 (C12-13) Pareth- 3ethoxylated, POE-6.5) 9. Polyethylene Cremophor ® A 25 68439-49-6 Sigma Aldrich (UK) glycol 1100 mono(hexadecyl/ octadecyl) ether 10. Linear alcohol Bio-soft N91-8 68439-46-3 Stephan (C9-11) Company (USA) ethoxylated POE -8 Pareth-3 11. Coceth-10 or Genapol ® C-100 61791-13-7 Sigma Aldrich (UK) Polyoxyethylene (10) dodecyl ether 12. Alcohols, C12-14, Rhodasurf ® LA 30 68439-50-9 Solvay Solutions ethoxylated Italia S.p.A. 13. Poly(ethylene Poly(ethylene 9004-74-4 Sigma Aldrich (UK) glycol) glycol) methyl ether methyl ether 14. C10-16 Pareth-1 Neodol ® PC 110 68002-97-1 Shell Chemical Company 15. PPG-11 Stearyl Arlamol ™ PS11E 25231-21-4 Croda (UK) Ether 16. Steareth-100 Brij ® S100 9005-00-9 Sigma Aldrich (UK) 17. Polyethylene Brij ® C-58 9004-95-9 Sigma Aldrich (UK) glycol hexadecyl ether 18. Pluronic ® F-127 Pluronic ® F-127 9003-11-6 Sigma Aldrich (UK) 19. Linear Alcohol Bio-soft N1-5 34398-01-1 Stepan Canada Inc. (C11) Ethoxylate, POE-5 20. Laureth-10 Intrasol FA 6540-99-4 Evonik Industries 12/18/10 AG 21. Decaethylene Polyoxyethylene 9002-92-0 Sigma Aldrich (UK) glycol (10) lauryl ether mono-dodecyl ether 22. Ethylene glycol 2- 109-86-4 Sigma Aldrich (UK) monomethyl ether Methoxyethanol 23. Myreth-4 Homulgator 27306-79-2 Grau Aromatics 920 G GmbH & Company KG 24. Oleth-16 Pegnol O-16A 25190-05-0 Toho Chemical Alkoxylated Industry Co., Ltd. Alcohols 25. Isosteareth-5 Emalex 1805 52292-17-8 Nihon Emulsion Company, Ltd. 26. PPG-10 Cetyl Arlamol ™ PC10 9035-85-2 Croda (UK) Ether 27. Polyoxy(ethylene Poly(ethylene 24938-91-8 Sigma-Aldrich (UK) glycol) (18) glycol) (18) tridecyl ether tridecyl ether 28. Poly(oxy-1,2- ALFONIC ® 10-8 26183-52-8 Sasol Chemicals ethanediyl), Ethoxylate (USA) LLC a-decyl- w-hydroxy- 29. Laureth-1 Mackam ™ 2LSF 4536-30-5 Rhodia (DE) 30. PEG-5 Ethox HTAM-5 61791-26-2 Ethox Chemicals, Hydrogenated Inc. Tallow Amine 31. PEG-15 Oleamine Nikkol 26635-93-8 Nikko Chemicals TAMNO-15 Co., Ltd. 32. Polyoxyethylene Brij ® O20-SS 9004-98-2 Sigma Aldrich (UK) (20) oleyl ether 33. Cetoleth-10 Brij ® CO10 8065-81-4 Croda, Inc. 34. Talloweth-7 Emulmin 70 61791-28-4 Sanyo Chemical Industries Ltd. 35. Isobutoxypropanol Isobutoxypropanol 34150-35-1 MolPort Alcohols 36. Isobutoxypropanol Isobutoxypropanol 23436-19-3 AKos Consulting Alcohols & Solutions 37. Diethylene Glycol Twincide EDG 111-46-6 Roda 38. Methoxyethanol Hisolve MC 109-86-4 Tolio Chemical Industry Co., Ltd. 39. Ethoxyethanol 2-Ethoxyethanol 110-80-5 Sigma-Aldrich (UK) Alcohols 40. Methoxyisopropanol Dowanol ™ PM 107-98-2 The Dow Alcohols Chemical Company 41. Methoxyethanol Hisolve MC 32718-54-0 Toho Chemical Industry Co., Ltd. 42. Methylal Dimethoxymethane 109-87-5 Sigma-Aldrich (UK) Ethers 43. 3-Methoxybutanol Methoxybutanol 2517-43-3 Hans Schwarzkopf GmbH/Co. KG 44. Butoxyethanol Butyl OXITOL 111-76-2 Shell Chemical Company 45. Propylene Glycol Dowanol ™ PnB 5131-66- The Dow n-Butyl Ether 8/29387- Chemical 86-8 Company 46. Propylene Glycol Propylene Glycol 15821-83-7 Sigma Aldrich (UK) Butyl Ether Butyl Ether 47. 2-(2- Diethylene glycol 112-34-5 Sigma Aldrich (UK) butoxyethoxy)ethanol butyl ether 48. Deceth-4 Phosphate Crodafos ™ D4A 52019-36-0 Croda, Inc. 49. 2- Ethylene glycol 2136-71-2 Sigma-Aldrich (UK) (Hexadecyloxy)ethanol monohexadecyl ether 50. Poly(propylene Poly(propylene 9003-13-8 Sigma-Aldrich (UK) glycol) glycol) monobutyl ether monobutyl ether 51. Propylene Glycol Dowanol ™ PnP 30136-13-1 The Dow Propyl Ether Chemical Company 52. Propylene Glycol Dowanol ™ PnB 29387-86- The Dow n-Butyl Ether 8/5131-66-8 Chemical Company 53. Dipropylene glycol Di(propylene 34590-94-8 Sigma Aldrich (UK) monomethyl ether glycol) methyl ether, mixture of isomers 54. Dipropylene Glycol Proglyde ™ DMM 111109-77-4 The Dow Dimethyl Ether Chemical Company 55. PPG-2 Methyl Ether Dowanol ™ DPM 13429-07-7 The Dow Chemical Company 56. Methoxydiglycol OriStar 111-77-3 Orient Stars LLC Ethers DEGME 57. Diethylene glycol Di(ethylene 111-90-0 Sigma Aldrich (UK) ethyl ether glycol) ethyl ether 58. Dimethoxydiglycol Dimethyldiglycol 111-96-6 H & V Chemicals Ethers 59. PPG-3 Methyl Ether Dowanol ™ TPM 37286-64-9 The Dow Chemical Company 60. Methyl Morpholine 224286 7529-22-8 Sigma-Aldrich (UK) Oxide Amine Oxides ALDRICH 4-Methylmorpholine N-oxide 61. Oleth-3 Brij ® O3 5274-66-8 Croda Europe, Ltd. 62. Tri(propylene Dowanol ™ TPnB 55934-93-5 Sigma-Aldrich (UK) glycol) n-butyl ether 63. Tripropylene Glycol Tripropylene Glycol 24800-44-0 Sigma-Aldrich (UK) 64. PPG-3 Methyl Ether Dowanol ™ TPM 25498-49-1 The Dow Alkoxylated Alcohols Chemical Company 65. Triethylene glycol Triglycol 112-27-6 Sigma Aldrich (UK) 66. PEG-3 Methyl Ether Hymol ™ 112-35-6 Toho Chemical Industry Co., Ltd. 67. Laureth-3 AEC Laureth-3 3055-94-5 A & E Connock (Perfumery & Cosmetics) Ltd. 68. Ethylhexylglycerin AG-G-75008 70445-33-9 Angene Chemical 69. Tetra(ethylene Tetraethylene 112-60-7 Sigma Aldrich (UK) glycol) glycol 70. Steareth-3 Isoxal 5 4439-32-1 Vevy Europe SpA 71. Ceteth-3 Emalex 103 4484-59-7 Nihon Emulsion Company, Ltd. 72. Myreth-3 Isoxal 5 26826-30-2 Vevy Europe SpA 73. Trideceth-3 Alfonic ® TDA-3 — Sasol North Ethoxylate America, Inc. 74. Ceteth-2 Brij ® C2 5274-61-3 Croda Europe, Ltd. 75. Oleth-2 Brij ® O2 5274-65-7 Croda, Inc. 76. Steareth-2 Brij ® S2 16057-43-5 Croda, Inc. 77. Cetoleth-10 Brij ® CO10 8065-81-4 Croda, Inc. 78. Trimethyl Pentanol Trimethyl Pentanol 68959-25-1 Angene Chemical Hydroxyethyl Hydroxyethyl Ether Alcohols Ether 79. Steareth-10 Allyl Ether Salcare ® SC80 109292-17-3 BASF 80. TEA-Lauryl Ether material ID- 1733-93-3 Angene Chemical AG-J-99109 81. Polyglyceryl-2 Chimexane NB 71032-90-1 Chimex Oleyl Ether 82. Batyl Alcohol B402 544-62-7 Sigma-Aldrich (UK) ALDRICH 83. Octaethylene Glycol 15879 5117-19-1 Sigma-Aldrich (UK) ALDRICH 84. Triglycerol Cithrol ™ 66082-42-6 Croda (UK) diisostearate 85. Diglycerin Diglycerin 801 59113-36-9 Sakamoto Yakuhin Kogyo Co., Ltd. 86. Polyglycerin #310 Polyglycerin #310 25618-55-7 Sakamoto Yakuhin Kogyo Co., Ltd. 87. Distearyl Ether Cosmacol ® SE 6297-03-6 Sasol Germany GmbH 88. Caprylyl Glyceryl Caprylyl Glyceryl 10438-94-5 AKos Consulting Ether Ether & Solutions 89. Chimyl Alcohol Chimyl Alcohol 506-03-6 Nikko Chemicals Co., Ltd. 90. Dipentaerythrityl Liponate ® DPC-6 68130-24-5 Lipo Chemicals, Hexacaprylate/ Inc. Hexacap rate 91. Morpholine 394467 110-91-8 Sigma-Aldrich (UK) ALDRICH 92. Dimethyl Oxazolidine OXABAN ™-A 51200-87-4 The Dow Chemical Company 93. Ethyl Hydroxymethyl 4- 68140-98-7 Angene Chemical Oleyl Oxazoline Oxazolemethanol 94. Methyl Hydroxymethyl Adeka Nol GE-RF 14408-42-5 Adeka Oleyl Oxazoline Corporation 95. Pramoxine HCl OriStar 637-58-1 Orient Stars LLC PMHCL 96. Allantoin Ascorbate Allantoin Ascorbate 57448-83-6 ABI Chem 97. Stearamidopropyl Mackalene ™ 326 55852-14-7 Rhodia Inc. Morpholine Lactate 98. Dioxolane Elcotal DX 646-06-0 Lambiotte & CIE S.A. 99. Glycerol Formal Glycerol Formal 5464-28-8 Sigma Aldrich (UK) 100. Stearamidopropyl Mackine 321 55852-13-6 Rhodia Inc. Morpholine 101. 2,4,6- Poly(melamine- 68002-20-0 Sigma-Aldrich (UK) Tris[bis(methoxy- co- methyl)amino]- formaldehyde) 1,3,5-triazine methylated 102. Poloxamine 1307 Pluracare ® 1307 11111-34-5 BASF 103. Nonoxynol-8 Igepal ® CO-610 27177-05-5 Rhodia Inc. 104. Nonoxynol-10 Igepal ® CO-710 27177-08-8 Rhodia Inc. 105. Octoxynol-10 Nikkol OP-10 2315-66-4 Nikko Chemicals Co., Ltd. 106. Nonoxynol-9 Igepal ® CO-630 68987-90-6 Rhodia Inc. 107. Nonoxynol-9 Nonoxynol-9 94349-40-3 Angene Chemical Iodine iodine 108. Octylphenoxy Igepal ® CA-630 68987-90-6 Rhodia Inc. poly(ethyleneoxy)ethanol, branched 109. Sodium Octoxynol-2 Triton ™ X-200 55837-16-6 The Dow Ethane Sulfonate Chemical Company 110. Benzylhemiformal Preventol D2 14548-60-8 Lanxess Corporation 111. Nonoxynol-2 Igepal ® CO-210 27176-93-8 Rhodia Inc. 112. Octoxynol-3 Igepal ® CA-420 2315-62-0 The Dow Chemical Company 113. Nonoxynol-3 Marlophen NP 3 27176-95-0 Sasol Germany GmbH 114. Alkoxylated Alkasurf NP-4 7311-27-5 Rhodia Inc. Alcohols 115. Nonoxynol-3 Triethylene 51437-95-7 Santa Cruz Glycol Mono(p- Biotechnology nonylphenyl) Ether 116. Nonoxynol-7 Lowenol 2689 27177-03-3 Jos. H Lowenstein & Sons, Inc. 117. Nonoxynol-6 Igepal ® CO-530 27177-01-1 Rhodia Inc. 118. Nonoxynol-5 Igepal ® CO-520 20636-48-0 Rhodia Inc. 119. Nonoxynol-5 Igepal ® CO-520 26264-02-8 Rhodia Inc. 120. Nonoxynol-5 Alkasurf NP-4 27176-97-2 Rhodia Inc. 121. Polyglyceryl-10 Nikkol 102051-00-3 Nikko Chemicals Trioleate Decaglyn 3-OV Co., Ltd. 122. Polyglyceryl-10 Nikkol 33940-99-7 Nikko Chemicals Dioleate Decaglyn 2-O Co., Ltd. 123. Polyglyceryl-10 Caprol 10G40 34424-98-1 Abitec Tetraoleate Corporation 124. Polyglyceryl-10 Nikkol 79777-30-3 Nikko Chemicals Stearate Decaglyn Co., Ltd. 1-SVEX 125. Polyglyceryl-10 S-Face O-1001 P 79665-93-3 Sakamoto Oleate Yakuhin Kogyo Co., Ltd. 126. Polyglyceryl-10 Nikkol 87390-32-7 Nikko Chemicals Myristate Decaglyn Co., Ltd. 1-MVEX 127. Dermofeel ® Dermofeel ® 34406-66-1 Dr. Straetmans G 10 L G 10 L 128. Polyglyceryl-6 NIKKOL 51033-38-6 Chemical Navi Laurate Hexaglyn 1-L 129. Polyglyceryl-6 S-Face IS-601 P 126928-07-2 Sakamoto Isostearate Yakuhin Kogyo Co., Ltd. 130. Choleth-10 Emalex CS-10 27321-96-6 Nihon Emulsion Company, Ltd. 131. Steareth-10 Allyl Salcare ® SC80 109292-17-3 BASF Ether/Acrylates Copolymer 132. Polyvinyl Stearyl Giovarez ®1800 9003-96-7 Phoenix Ether Chemical, Inc. 133. Dicetyl Ether Cosmacol Ether 16 — Sasol Germany GmbH 134. PPG-23-Steareth-34 Unisafe 34S-23 9038-43-1 Pola Chemical Industries, Inc. 135. Stearoxypropyl Farmin DM E-80 17517-01-0 Kao Corp. Dimethylamine 136. Distearyl Ether Cosmacol SE 6297-03-6 Sasol Germany GmbH 137. Polyquaternium-10 AEC 55353-19-0 A & E Connock Polyquaternium-10 (Perfumery & Cosmetics) Ltd. 138. Octyl ether Dioctyl ether 629-82-3 Sigma Adirich (UK) 139. Ethyl Ether Diethyl Ether 60-29-7 EMD Chemicals 140. Methyl Hexyl methyl hexyl 4747-07-3 TCI AMERICA Ether Ethers ether 141. Ceteth-12 Emalex 112 94159-75-8 Nihon Emulsion Company, Ltd. 142. Ceteth-10 or cetyl Jeecol CA-10 14529-40-9 Jeen alcohol POE-10 International 143. Steareth-10 Jeecol SA-10 13149-86-5 Jeen International 144. Nonaethylene glycol Nonaethylene glycol 3055-99-0 Sigma Aldrich (UK) monododecyl ether monododecyl ether 145. Oleth-10 Brij ® O10 71976-00-6 Croda, Inc. 146. Oleth-10 Brij ® O10 24871-34-9 Croda, Inc. 147. PEG-12 Carbowax ™ 6790-09-6 The Dow PEG 600 Chemical Company 148. PEG-9 Sabopeg 400 3386-18-3 Sabo s.p.a. 149. PEG-10 DECAETHYLENE 5579-66-8 MolPort GLYCOL 150. PEG-6 Carbowax ™ 2615-15-8 The Dow PEG 300 Chemical Company 151. Glycerol Glycerol 25791-96-2 Sigma Aldrich (UK) propoxylate propoxylate 152. Glycerol Glycerol 31694-55-0 Sigma Aldrich (UK) ethoxylate ethoxylate 153. Laureth-8 AEC 3055-98-9 A & E Connock Laureth-8 (Perfumery & Cosmetics) Ltd. 154. Oleth-8 Emalex 508 27040-03-5 Nihon Emulsion Company, Ltd. 155. Laureth-7 Alfonic 3055-97-8 Sasol North 1216CO-7 America, Inc. Ethoxylate 156. Steareth-7 Polyoxyethylene 66146-84-7 Sigma Aldrich (7) stearyl ether 157. Deceth-6 Alfonic 1012- 5168-89-8 Sasol North 6.0 Ethoxylate America, Inc. 158. Steareth-6 Emalex 606 2420-29-3 Nihon Emulsion Company, Ltd. 159. Hexaethylene glycol Hexaethylene glycol 3055-96-7 Sigma-Aldrich (UK) monododecyl ether monododecyl ether 160. Hexaethylene glycol Hexaethylene glycol 5168-91-2 Sigma-Aldrich (UK) monohexadecyl ether monohexadecyl ether 161. Beheneth-5 Nikkol BB-5 136207-49-3 Nikko Chemicals Co., Ltd. 162. Myreth-5 Isoxal 12 92669-01-7 Vevy Europe SpA 163. Steareth-5 Jeecol SA-5 71093-13-5 Jeen International Corporation 164. Ceteth-5 Emalex 105 4478-97-1 Nihon Emulsion Company, Ltd. 165. Oleth-5 Brij ® O5 5353-27-5 Croda, Inc. 166. Laureth-5 Safol ® 23E5 3055-95-6 Sasol North Ethoxylate America, Inc. 167. Steareth-4 Jeecol SA-4 59970-10-4 Jeen International Corporation 168. Laureth-4 Brij ® L4 5274-68-0 Croda, Inc. 169. Myreth-4 Homulgator 920 G 39034-24-7 Grau Aromatics GmbH & Company KG 170. Ceteth-4 Procol CA-4 5274-63-5 Protameen Chemicals 171. Oleth-4 Chemal OA-4 5353-26-4 Chemax, Inc. 172. Oleth-4 Chemal OA-4 103622-85-1 Chemax, Inc. 173. Polyimide-1 Aquaflex ™ 497926-97-3 Chemwill XL-30 174. Polymethoxy Bicyclic Caswell No. 56709-13-8 Angene Chemical Oxazolidine 494CA 175. Hydroxymethyl Zoldine ™ ZT 6542-37-6 Angus Chemical Dioxoazabicyclooctane Company 176. Dihydro-7a- 5-Ethyl-1-aza- 7747-35-5 Sigma Aldrich (UK) ethyloxazolo[3,4- 3,7-dioxabicy- c]oxazole clo[3.3.0]octane 177. Dibenzylidene Disorbene ® 32647-67-9 Roquette Sorbitol America, Inc. 178. Dimethyldibenzylidene Millad ® 3988 135861-56-2 Milliken Sorbitol Chemicals 179. Laureth-2 Alfonic 3055-93-4 Sasol North 1216CO-2 America, Inc. Ethoxylate 180. 2-(2- Piperonyl 51-03-6 Sigma-Aldrich (UK) Butoxyethoxy)ethyl Butoxide (6-propylpiperonyl) ether 181. Menthone Frescolat ® 63187-91-7 Symrise Glycerin Acetal MGA 182. Propylene Glycol Mackaderm 68332-79-6 Rhodia Inc. Caprylate PGC 183. Diethoxynonadiene SBB016951 67674-36-6 Ambinter 184. Menthoxypropanediol Coolact ® 10 87061-04-9 Takasago Alcohols International Corporation 185. 2-Diphenylmethoxy- Diphenhydramine 147-24-0 Sigma-Aldrich (UK) N,N- HCl dimethylethylamine hydrochloride 186. 3-((2-ethyl- — 70445-33-9 — hexyl)oxy)propane- 1,2-diol 187. 3-((2-propyl- — — — heptyl)oxy)propane- 1,2-diol 188. 1-amino-3-((2- — 99509-00-9 — ethylhexyl)oxy)propan- 2-ol 189. 1-(1-Methyl-2- Di(propylene 29911-27-1 Sigma Aldrich (UK) propoxyethoxy)- glycol) propyl 2-propanol ether

As described further herein. The compounds, as described above in Tables 1(a) and 1(b), act as a substantially non-odorous fragrance modulator of fragrance materials of the present invention. Without wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulators associate to fragrance materials to allow for high or overdosed wt % values of the fragrance materials (e.g., greater than 30 wt %) in a composition to which the coating contacts will allow the overdosed fragrance materials to drive the perceived character of the fragrance, while mitigating or eliminating a perceived harshness of the composition by the user. The non-odorous fragrance modulators can also be used in materials that do not include overdosed fragrance materials.

The composition including the substantially non-odorous fragrance modulator according to the present invention, can include a volatile solvent, a non-volatile solvent, or a mixture thereof. The solvent can be organic or aqueous. Where present, the volatile solvent can be present in the amount of from about 20 wt % to about 99 wt % c relative to the total weight of the composition, about 30 wt % to about 80 wt %, about 55 wt % to about 75 wt %, or less than, equal to, or greater than about 20 wt %, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, or about 99 wt %, and wherein the solvent is a branch or unbranched C₁ to C₁₀ alkyl, alkenyl or alkynyl group having at least one alcohol moiety, preferably ethanol, or isopropanol, or other alcohols (e.g., methanol, propanol, isopropanol, butanol, and mixtures thereof) commonly found in commercial fine fragrance products.

Accordingly, ethanol may be present in any of the compositions of the present invention, and more specifically, it will form from about 5 wt % to about 95 wt %, or even from about 10 wt % to about 80 wt %, 25 wt % to about 75 wt % of the composition, or combinations thereof, relative to the total weight of the composition. Alternatively, ethanol may be present in an amount of from about 10 wt % or 25 wt % to about 75 wt % or 80 wt %, relative to the total weight of the composition. The ethanol useful in the present invention may be any acceptable quality of ethanol, compatible and safe for the specific intended use of the composition such as, for example, topical applications of fine fragrance or cosmetic compositions.

The composition may comprise a non-volatile solvent or a mixture of non-volatile solvents. Non-limiting examples of non-volatile solvents include benzyl benzoate, diethyl phthalate, isopropyl myristate, propylene glycol, dipropylene glycol, triethyl citrate, and mixtures thereof. Where non-volatile solvents are present, introduced either with the perfume materials or separately, then for the purposes of calculating the proportion of fragrance component having a vapor pressure of less than 0.001 Torr (0.000133 kPa) at 25° C. the total fragrance components does not include non-volatile solvents. Where non-volatile solvents are present, introduced either with the perfume materials or separately, then for the purposes of calculating the total level of fragrance component this does not include non-volatile solvents. In addition, if present with cyclic oligosaccharides, the non-volatile solvent may be included at a weight ratio of the non-volatile solvent to the cyclic oligosaccharide of less than 1:1, less than 1:2, less than 1:10, or less than 1:100.

In some examples (e.g., those including a volatile solvent), water may be present in any of the compositions of the present invention, and more specifically, it may not exceed about 95 wt % relative to the total weight of the composition, about 90 wt % or less, about 85 wt % or less, about 80 wt % or less, about 75 wt % or less, about 70 wt % or less, about 65 wt % or less, about 60 wt % or less, about 55 wt % or less, about 50 wt % or less, about 45 wt % or less, about 40 wt % or less, about 35 wt % or less, about 30 wt % or less, about 20 wt % or less, about 10 wt %, or less than, equal to, or greater than about 95 wt %, 90, 85, 80, 75, 70, 65, 60, 55, 50, 45, 40, 30, 35, 30, 25, 20, 15, 10, or 5 wt %. Alternatively, water may be present in an amount of from about 5 wt % or about 95 wt % When the composition is a cosmetic composition the level of water should not be so high that the product becomes cloudy thus negatively impacting the product aesthetics. It is understood that the amount of water present in the composition may be from the water present in the volatile solvent (e.g., ethanol) used in the composition, as the case may be. In some examples, the coating composition contains only substantially non-odorous components.

The coating compositions described herein can be used in conjunction with a fragrance composition. The fragrance composition can include one or more fragrance components that can be characterized by their respective volatilities. For example, fragrance components can be low volatility, moderate volatility, or high volatility fragrance components. According to various embodiments, a fragrance composition can be overdosed with one or more of the fragrance components such that fragrance composition can be considered to be a bottom-heavy fragrance, a middle-heavy fragrance, a top-heavy fragrance composition, or a composition where fragrance components are evenly distributed.

Each group of materials can be associated with various perceptions by a panel of experts or professional evaluators or individual experts or professional evaluators. While not so limited, a high volatile fragrance may be associated with a citrus character; a moderate volatile fragrance may be associated with a spicy character; and a low volatile fragrance may be associated with a woody character. Each group of fragrance materials can include synthetic materials or natural materials. The volatility of the fragrance materials can be in reference to an individual fragrance material. Alternatively, in cases where a combination of materials produce a fragrance the volatility may be in reference to that aggregation.

With respect to a fragrance composition, the fragrance component can be present in an amount of from about 0.04 wt % to 30 wt %, 1 wt % to about 30 wt %, about 5 wt % to about 30 wt %, or less than, equal to, or greater than about 0.04 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.5, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt % relative to the composition. Additional components in the fragrance composition can include a carrier such as the organic, inorganic, or aqueous carriers described herein with respect to the coating composition.

Additionally, according to various embodiments, it is possible for the fragrance composition to include any one or more of the modulators described herein with respect to the coating composition. Where present in the coating composition, the modulator can be present in an amount of from about 0.1 wt % to about 20 wt %, about 0.5 wt % to about 20 wt %, or less than, equal to, or greater than about 0.1 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, or about 20 wt % relative to the coating composition.

As described herein, the “fragrance materials” have been classified as low, moderate or high volatile fragrance materials according to their volatility by their vapor pressure. This method of classifying fragrance materials by their vapor pressure avoids the problem of different classifications for the same fragrance material according to the traditional approach that relies on their subjective characteristic character. In the case that the fragrance materials are a natural oil, extract or absolute, which comprises a mixture of several compounds, the vapor pressure of the complete oil should be treated a mixture of the individual perfume raw material components using the reference program cited above. The individual components and their level, in any given natural oil or extract, can be determined by direct injection of the oil into a GC-MS column for analysis as known by one skilled in the art. In the scenario that the fragrance materials are a proprietary specialty accord, so called ‘bases’, the vapor pressure, using the reference program cited above, should preferably be obtained from the supplier. However, it is understood by one skilled in the art that they can physically analyze the composition of a full fragrance oil available commercially to identity the fragrance raw materials and their levels using standard GC-MS techniques. This would be irrespective of whether they had been added to the fragrance oil as individual chemicals, as components of naturals or from proprietary bases. Although proprietary bases and naturals are included in our examples, when analyzing a commercially available fragrance via GC-MS one could simply identify the components of the base or natural oil as part of the overall fragrance mixture and their levels, without being able to identify which proprietary base or natural oil the fragrance had come from.

Low Volatile Fragrance Materials

The fragrance component comprises at least one low volatile fragrance material. Individual low volatile fragrance materials or aggregate low volatile fragrance materials are those having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. According to some examples, the composition can include at least 3 low volatile fragrance materials, or at least 4 low volatile fragrance materials, or at least 5 low volatile fragrance materials, or at least 7 low volatile fragrance materials. The amount of the low volatile fragrance material present in the fragrance component can vary depending on the specific application. In some embodiments, the low volatile fragrance component can be in a range of from about 0 wt % to about 100 wt % of the fragrance component, about 10 wt % to about 90 wt %, about 20 wt % to about 80 wt %, about 30 wt % to about 70 wt %, or about 40 wt % to about 60 wt %. The exact wt % of the low volatile fragrance component can vary greatly based on the fragrance's construction, for example, in a bottom-heavy embodiment, the low volatile fragrance material can be greater than about 30 wt % of the fragrance component, greater than about 40 wt %, greater than about 50 wt %, greater than about 60 wt %, about 31 wt % to about 60 wt %, about 40 wt % to about 50 wt %, or less than, equal to, or greater than about 30 wt %, 31, 35, 40, 45, 50, 55, 60, 65, 70, or 75 wt %. In embodiments that are top- or middle-heavy the low volatile fragrances can be can be present in an amount ranging from about 0 wt % to about 30 wt % of the fragrance component, about 1 wt % to about 30 wt %, about 1 wt % to about 29 wt %, or less than, equal to, or greater than about 0 wt %, 0.1, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.25, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt %. In still further embodiments, the low volatile fragrance material can be in an amount ranging from about 30 wt % to about 40 wt % of the fragrance component, about 32 wt % to about 35 wt %, less than, equal to, or greater than about 30 wt % 31, 32, 33, 34, 35, 36, 37, 38, 39, or 40 wt %. In some embodiments, the low-volatile fragrance material can be the only fragrance material present. Relative to any other fragrance materials, the low volatile fragrance component can be present in a ratio ranging from about 20:1 to about 1:20, about 10:1 to about 1:10, about 5:1 to about 1:5, or about 1:1.

If there are more than one low volatile fragrance materials, then the ranges provided hereinabove cover the total of all the low volatile fragrance materials. Examples of suitable low volatile fragrances materials are provided in Table 2A and 2B below.

Preferably, the low volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7, at least 8, at least 10, or at least 12 low volatile fragrance materials as disclosed in Table 2A. Natural fragrance materials or oils having an aggregate vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. are provided in Table 2B. Low Volatile Natural Oils.

TABLE 2A Low Volatile Fragrance Materials Vapor Pressure No. CAS Number IUPAC Name Common Name** (Torr at 25° C.)* 1. 1211-29-6 Cyclopentaneacetic acid, Methyl 0.00096500 3-oxo-2-(2Z)-2-penten-1- jasmonate yl-, methyl ester, (1R,2R)- 2. 28219-60-5 2-Buten-1-ol, 2-methyl- Hindinol 0.00096100 4-(2,2,3-trimethyl-3- cyclopenten-1-yl)- 3. 93-08-3 Ethanone, 1-(2- Methyl beta- 0.00095700 naphthalenyl)- naphthyl ketone 4 67633-95-8 3-Decanone, 1-hydroxy- Methyl 0.00095100 Lavender Ketone 5. 198404-98-7 Cyclopropanemethanol, Javanol ® 0.00090200 1-methyl-2-[(1,2,2- trimethylbicyclo[3.1.0]hex- 3-yl)methyl]- 6. 121-32-4 Benzaldehyde, 3-ethoxy- Ethyl vanillin 0.00088400 4-hydroxy- 7. 72403-67-9 3-Cyclohexene-1- Myraldylacetate 0.00087900 methanol, 4-(4-methyl-3- penten-1-yl)-, 1-acetate 8. 28940-11-6 2H-1,5-Benzodioxepin- Calone 0.00083100 3(4H)-one, 7-methyl- 9. 139504-68-0 2-Butanol, 1-[[2-(1,1- Amber core 0.00080300 dimethylethyl)cyclohexyl]oxy]- 10. 502847-01-0 Spiro[5.5]undec- Spiro[5.5]undec- 0.00073100 8-en-1-one, 8-en-1-one, 2,2,7,9-tetramethyl- 2,2,7,9-tetramethyl- 11. 2570-03-8 Cyclopentaneacetic acid, trans-Hedione 0.00071000 3-oxo-2-pentyl-, methyl ester, (1R,2R)-rel- 12. 24851-98-7 Cyclopentaneacetic acid, Methyl 0.00071000 3-oxo-2-pentyl-, methyl dihydrojasmonate ester or alternatives ¹ 13. 101-86-0 Octanal, 2- Hexyl 0.00069700 (phenylmethylene)- cinnamic aldehyde 14. 365411-50-3 Indeno[4,5-d]-1,3-dioxin, Nebulone 0.00069200 4,4a,5,6,7,8,9,9b- octahydro-7,7,8,9,9- pentamethyl- 15. 37172-53-5 Cyclopentanecarboxylic Dihydro Iso 0.00067500 acid, 2-hexyl-3-oxo-, Jasmonate methyl ester 16. 65113-99-7 3-Cyclopentene-1- Sandalore ® 0.00062500 butanol, α,β,3,2,2,3- pentamethyl- 17. 68133-79-9 Cyclopentanone, 2-(3,7- Apritone 0.00062000 dimethyl-2,6-octadien-1- yl)- 18. 7212-44-4 1,6,10-Dodecatrien-3-ol, Nerolidol 0.00061600 3,7,11-trimethyl- 19. 53243-59-7 2-Pentenenitrile, 3- Citronitril 0.00061500 methyl-5-phenyl-, (2Z)- 20. 134123-93-6 Benzenepropanenitrile, Fleuranil 0.00057600 4-ethyl-α,α-dimethyl- 21. 77-53-2 1H-3a,7-Methanoazulen- Cedrol Crude 0.00056900 6-ol, octahydro-3,6,8,8- tetramethyl-, (3R,3aS,6R,7R,8aS)- 22. 68155-66-8 Ethanone, 1- Iso Gamma 0.00056500 (1,2,3,5,6,7,8,8a- Super octahydro-2,3,8,8- tetramethyl-2- naphthalenyl)- 23. 54464-57-2 Ethanone, 1- Iso-E Super ® 0.00053800 (1,2,3,4,5,6,7,8- octahydro-2,3,8,8- tetramethyl-2- naphthalenyl)- 24. 774-55-0 Ethanone, 1-(5,6,7,8- Florantone 0.00053000 tetrahydro-2- naphthalenyl)- 25. 141-92-4 2-Octanol, 8,8- Hydroxycitronellal 0.00052000 dimethoxy-2,6- Dimethyl dimethyl- Acetal 26. 20665-85-4 Propanoic acid, 2- Vanillin 0.00051200 methyl-, 4-formyl-2- isobutyrate methoxyphenyl ester 27. 79-78-7 1,6-Heptadien-3-one, 1- Hexalon 0.00049800 (2,6,6-trimethyl-2- cyclohexen-1-yl)- 28. 6259-76-3 Benzoic acid, 2-hydroxy-, Hexyl 0.00049100 hexyl ester Salicylate 29. 93-99-2 Benzoic acid, phenyl Phenyl 0.00047900 ester Benzoate 30. 153859-23-5 Cyclohexanepropanol, Norlimbanol 0.00046900 2,2,6-trimethyl-α-propyl-, (1R,6S)- 31. 70788-30-6 Cyclohexanepropanol, Timberol/ 0.00046900 2,2,6-trimethyl-α-propyl- Norlimbanol 32. 68555-58-8 Benzoic acid, 2-hydroxy-, Prenyl 0.00045700 3-methyl-2-buten-1-yl Salicylate ester 33. 950919-28-5 2H-1,5-Benzodioxepin- Cascalone 0.00045500 3(4H)-one, 7-(1- methylethyl)- 34. 30168-23-1 Butanal, 4-(octahydro- Dupical 0.00044100 4,7-methano-5H-inden-5- ylidene)- 35. 1222-05-5 Cyclopenta[g]-2-, Galaxolide ® 0.00041400 benzopyran, 1,3,4,7,8- hexahydro-4,6,6,7,8,8- hexamethyl- 36. 4602-84-0 2,6,10-Dodecatrien-1-ol, Farnesol 0.00037000 3,7,11-trimethyl- 37. 95962-14-4 Cyclopentanone, 2-[2-(4- Nectaryl 0.00036700 methyl-3-cyclohexen-1- yl)propyl]- 38. 4674-50-4 2(3H)-Naphthalenone, Nootkatone 0.00035800 4,4a,5,6,7,8-hexahydro- 4,4a-dimethyl-6-(1- methylethenyl)-, (4R,4aS,6R)- 39. 3487-99-8 2-Propenoic acid, 3- Amyl 0.00035200 phenyl-, pentyl ester Cinnamate 40. 10522-41-5 2-hydroxy-2-phenylethyl Styrolyl 0.00033900 acetate Acetate 41. 118-71-8 4H-Pyran-4-one, 3- Maltol 0.00033700 hydroxy-2-methyl- 42. 128119-70-0 1-Propanol, 2-methyl-3- Bornafix 0.00033400 [(1,7,7-tri- methylbicyclo[2.2.1]hept- 2-yl)oxy]- 43. 103614-86-4 1-Naphthalenol, Octalynol 0.00033200 1,2,3,4,4a,5,8,8a- octahydro-2,2,6,8- tetramethyl- 44. 7785-33-3 2-Butenoic acid, 2- Geranyl 0.00033200 methyl-, (2E)-3,7- Tiglate dimethyl-2,6-octadien-1- yl ester, (2E)- 45. 117933-89-8 1,3-Dioxane, 2-(2,4- Karanal 0.00033100 dimethyl-3-cyclohexen- 1-yl)-5-methyl-5-(1- methylpropyl)- 46. 629-92-5 Nonadecane Nonadecane 0.00032500 47. 67801-20-1 4-Penten-2-ol, 3-methyl- Ebanol 0.00028100 5-(2,2,3-trimethyl-3- cyclopenten-1-yl)- 48. 65416-14-0 Propanoic acid, 2- Maltol 0.00028000 methyl-, 2-methyl-4-oxo- Isobutyrate 4H-pyran-3-yl ester 49. 28219-61-6 2-Buten-1-ol, 2-ethyl-4- Laevo 0.00028000 (2,2,3-trimethyl-3- Trisandol cyclopenten-1-yl)- 50. 5986-55-0 1,6-Methanonaphthalen- Healingwood 0.00027800 1(2H)-ol, octahydro- 4,8a,9,9-tetramethyl-, (1R,4S,4aS,6R,8aS)- 51. 195251-91-3 2H-1,5-Benzodioxepin- Transluzone 0.00026500 3(4H)-one, 7-(1,1- dimethylethyl)- 52. 3100-36-5 8- Cyclohexadecen-1-one Cyclohexadecenone 0.00025300 53. 65405-77-8 Benzoic acid, 2-hydroxy-, cis-3-Hexenyl 0.00024600 (3Z)-3-hexen-1-yl ester salicylate 54. 4940-11-8 4H-Pyran-4-one, 2-ethyl- Ethyl Maltol 0.00022800 3-hydroxy- 55. 541-91-3 Cyclopentadecanone, 3- Muskone 0.00017600 methyl- 56. 118-58-1 Benzoic acid, 2-hydroxy-, Benzyl 0.00017500 phenylmethyl ester salicylate 57. 81783-01-9 6,8-Nonadien-3-one, Labienoxime 0.00017300 2,4,4,7-tetramethyl-, oxime 58. 25485-88-5 Benzoic acid, 2-hydroxy-, Cyclohexyl 0.00017300 cyclohexyl ester Salicylate 59. 91-87-2 Benzene, [2- Amyl 0.00016300 (dimethoxymethyl)-1- Cinnamic hepten-1-yl]- Aldehyde Dimethyl Acetal 60. 104864-90-6 3-Cyclopentene-1- Firsantol 0.00016000 butanol, β,2,2,3- tetramethyl-δ-methylene- 61. 224031-70-3 4-Penten-1-one, 1- Spirogalbanone 0.00015300 spiro[4.5]dec-7-en-7-yl- 62. 134-28-1 5-Azulenemethanol, Guaiyl 0.00013400 1,2,3,4,5,6,7,8- Acetate octahydro-α,α,3,8- tetramethyl-, 5-acetate, (3S,5R,8S)- 63. 236391-76-7 Acetic acid, 2-(1- Romandolide ® 0.00012400 oxopropoxy)-, 1-(3,3- dimethylcyclohexy)ethyl ester 64. 115-71-9 2-Penten-1-ol, 5- cis-alpha- 0.00011800 [(1R,3R,6S)-2,3- Santalol dimethyltricy- clo[2.2.1.02,6]hept- 3-yl]-2-methyl-, (2Z)- 65. 107898-54-4 4-Penten-2-ol, 3,3- Polysantol ® 0.00011700 dimethyl-5-(2,2,3- trimethyl-3-cyclopenten- 1-yl)- 66. 69486-14-2 5,8-Methano-2H-1- Florex ® 0.00011000 benzopyran-2-one, 6- ethylideneoctahydro- 67. 84697-09-6 Heptanal, 2-[(4- Acalea 0.00010100 methylphenyl)methylene]- 68. 14595-54-1 4-Cyclopentadecen-1- Exaltenone 0.00009640 one, (4Z)- 69. 32388-55-9 Ethanone, 1- Vertofix ® 0.00008490 [(3R,3aR,7R,8aS)- 2,3,4,7,8,8a-hexahydro- 3,6,8,8-tetramethyl-1H- 3a,7-methanoazulen-5- yl]- 70. 131812-67-4 1,3-Dioxolane, 2,4- Okoumal ® 0.00007600 dimethyl-2-(5,6,7,8- tetrahydro-5,5,8,8- tetramethyl-2- naphthalenyl)- 71. 106-02-5 Oxacyclohexadecan-2- Exaltolide ® 0.00006430 one 72. 141773-73-1 1-Propanol, 2-[1-(3,3- Helvetolide ® 0.00005790 dimethylcy- clohexyl)ethoxy]-2- methyl-, 1-propanoate 73. 63314-79-4 5-Cyclopentadecen-1- Delta 0.00005650 one, 3-methyl- Muscenone 74. 77-42-9 2-Penten-1-ol, 2-methyl- cis-beta- 0.00004810 5-[(1S,2R,4R)-2-methyl-3- Santalol methylenebicyclo[2.2.1]hept- 2-yl]-, (2Z)- 75. 362467-67-2 2H-1,5-Benzodioxepin- Azurone 0.00004770 3(4H)-one, 7-(3- methylbutyl)- 76. 28371-99-5 Ethanone, 1-(2,6,10- Trimofix O 0.00004580 trimethyl-2,5,9- cyclododecatrien-1-yl)- 77. 16223-63-5 1H-3a,6- Khusimol 0.00004400 Methanoazulene-3- methanol, octahydro-7,7- dimethyl-8-methylene-, (3S,3aR,6R,8aS)- 78. 10461-98-0 Benzeneacetonitrile, α- Peonile 0.00004290 cyclohexylidene- 79. 90-17-5 Benzenemethanol, α- Rosacetol 0.00004240 (trichloromethyl)-, 1- acetate 80. 50607-64-2 Benzoic acid, 2-[(2- Mevantraal 0.00004070 methylpentylidene)amino]-, methyl ester 81. 29895-73-6 5-Hydroxy-2-benzyl-1,3- Acetal CD 0.00004050 dioxane 82. 94-47-3 Benzoic acid, 2- Phenyl Ethyl 0.00003480 phenylethyl ester Benzoate 83. 3100-36-5 Cyclohexadec-8-en-1- Globanone ® 0.00003310 one 84. 37609-25-9 5-Cyclohexadecen-1-One Ambretone 0.00003310 85. 66072-32-0 Cyclohexanol, 4-(1,7,7-tri- Iso Bornyl 0.00003010 methylbicyclo[2.2.1]hept- Cyclohexanol 2-yl)- 86. 31906-04-4 3-Cyclohexene-1- Lyral ® 0.00002940 carboxaldehyde, 4-(4- hydroxy-4- methylpentyl)- 87. 21145-77-7 Ethanone, 1-(5,6,7,8- Musk Plus 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyl-2- naphthalenyl)- 88. 21145-77-7 Ethanone, 1-(5,6,7,8- Fixolide 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyl-2- naphthalenyl)- 89. 22442-01-9 2-Cyclopentadecen-1- Muscenone 0.00002770 one, 3-methyl- 90. 109-29-5 Oxacycloheptadecan-2- Silvanone Ci 0.00002600 one 91. 101-94-0 Benzeneacetic acid, 4- Para Cresyl 0.00002330 methylphenyl ester Phenyl Acetate 92. 102-20-5 Benzeneacetic acid, 2- Phenyl Ethyl 0.00002300 phenylethyl ester Phenyl Acetate 93. 118562-73-5 Cyclododecaneethanol, Hydroxyambran 0.00001800 β-methyl- 94. 103-41-3 2-Propenoic acid, 3- Benzyl 0.00001050 phenyl-, phenylmethyl Cinnamate ester 95. 4707-47-5 Benzoic acid, 2,4- Veramoss/ 0.00001050 dihydroxy-3,6-dimethyl-, LRG201/ methyl ester Evernyl 96. 183551-83-9 Naphtho[2,1-b]furan- Myrrhone 0.00000977 6(7H)-one, 8,9-dihydro- 1,5,8-trimethyl-, (8R)- 97. 102-17-0 Benzeneacetic acid, (4- Para Anisyl 0.00000813 methoxyphenyl)methyl Phenyl Acetate ester 98. 120-11-6 Benzene, 2-methoxy-1- Benzyl Iso 0.00000676 (phenylmethoxy)-4-(1- Eugenol propen-1-yl)- 99. 102-22-7 Benzeneacetic acid, (2E)- Geranyl 0.00000645 3,7-dimethyl-2,6- Phenylacetate octadien-1-yl ester 100. 111879-80-2 Oxacyclohexadec-12-en- Habanolide 0.00000431 2-one, (12E)- 100% 101. 87-22-9 Benzoic acid, 2-hydroxy-, Phenyl Ethyl 0.00000299 2-phenylethyl ester Salicylate 102. 78-37-5 2-Propenoic acid, 3- Linalyl 0.00000174 phenyl -, 1-ethenyl-1,5- Cinnamate dimethyl-4-hexen-1-yl ester 103. 28645-51-4 Oxacycloheptadec-10-en- Ambrettolide 0.00000139 2-one 104. 123-69-3 Oxacycloheptadec-8-en- Ambrettolide 0.00000136 2-one, (8Z)- 105. 3391-83-1 1,7- Musk RI 0.00000057 Dioxacycloheptadecan-8- one 106. 68527-79-7 7-Octen-2-ol, 8-(1H- Indolene 0.000000445 indol-1-yl)-2,6-dimethyl- 107. 89-43-0 Methyl 2-[(7-hydroxy- Aurantinol 0.0000000100 3,7-dimethyloc- tylidene)amino]benzoate 108. 54982-83-1 1,4- Zenolide 0.00000000834 Dioxacyclohexadecane- 5,16-dione 109. 105-95-3 1,4- Ethylene 0.00000000313 Dioxacycloheptadecane- Brassylate 5,17-dione 110. 3681-73-0 Hexadecanoic acid, (2E)- Hexarose 0.00000000300 3,7-dimethyl-2,6- octadien-1-yl ester 111. 4159-29-9 Phenol, 4-[3- Coniferyl 0.00000000170 (benzoyloxy)-1-propen- benzoate 1-yl]-2-methoxy- 112. 144761-91-1 Benzoic acid, 2-[(1- Trifone DIPG 0.00000000093 hydroxy-3- phenylbutyl)amino]-, methyl ester ¹ Non-limiting examples of alternative qualities from various suppliers can be purchased under the following tradenames: Kharismal ® Super (IFF), Kharismal ® (IFF), Hedione ® (Firmenich), Hedione ® HC (Firmenich), Paradisone (Firmenich), Cepionate (Zenon), Super cepionate (Zenon), Claigeon ® (Zenon). *Vapor Pressures are acquired as described in the Test Methods Section. **Origin: The low volatile fragrance materials may be obtained from one or more of the following companies: Firmenich (Geneva, Switzerland), Symrise AG (Holzminden, Germany), Givaudan (Argenteuil, France), IFF (Hazlet, New Jersey), Bedoukian (Danbury, Connecticut), Sigma Aldrich (St. Louis, Missouri), Millennium Specialty Chemicals (Olympia Fields, Illinois), Polarone International (Jersey City, New Jersey), and Aroma & Flavor Specialties (Danbury, Connecticut).

TABLE 2B Low Volatile Natural Oils. No. Natural oil Supplier 1. Beeswax Absolute Robertet 2. Cedarwood Sawdust SFE Firmenich 3. Cedarwood Oil Rect Firmenich 4. Cedarwood Texas Light H. Reynaud & Fils 5. Ciste Absolute IFF 6. Cocoa Colorless Oil Robertet 7. Cypriol Coeur Essence Robertet 8.. Guaiacwood Oil Global Essence Inc 9. Incense Wood Natural Robertet 10. Orris CO2 Extract Mane 11. Patchouli Oil IFF 12. Tolu Baume Res Robertet 13. Vanilla Absolute Robertet 14. Vanilla CO2 Absolute Robertet 15. Vetivert Oil IFF 16. Vetyvert Acetate Robertet

Suppliers: Firmenich, Geneva, Switzerland Global Essence Inc, New Jersey, USA H. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, N.J., USA Mane, Le Bar-sur-Loup, France Robertet, Grasse, France

Exemplary low volatile fragrance materials selected from the group of Tables 2A or 2B Low Volatile Fragrance Materials are preferred. However, it is understood by one skilled in the art that other low volatile fragrance materials, not recited in Tables 2A or 2B, would also fall within the scope of the present invention, so long as they have a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C.

Moderate Volatile Fragrance Materials

The fragrance component includes at least one moderate volatile fragrance material or aggregate of volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. In some examples, the composition according to the present disclosure can include at least 3 moderate volatile fragrance materials, or at least 5 moderate volatile fragrance materials, or at least 7 moderate volatile fragrance materials. Compositions of the present invention can include any suitable amount of the moderate volatile fragrance materials. For example, in some embodiments, the moderate volatile fragrance component can be in a range of from about 0 wt % to about 100 wt % of the fragrance component, about 10 wt % to about 90 wt %, about 20 wt % to about 80 wt %, about 30 wt % to about 70 wt %, or about 40 wt % to about 60 wt %. The exact wt % of the moderate volatile fragrance component can vary greatly based on the fragrance's construction. The exact wt % of various moderate volatile fragrance components can depend on the fragrance's construction. For example, in some constructions, high levels of the moderate volatile fragrance materials present in an amount of from about 30 wt % to about 75 wt %, about 35 wt % to about 60 wt %, or less than equal to, or greater than about 30 wt %, 35, 40, 45, 50, 55, 60, 65, 70, or 75 wt % of the fragrance component. If there are more than one moderate volatile fragrance materials, then the ranges provided hereinabove cover the total of all of the moderate volatile fragrance materials. Suitable examples of moderate volatile fragrances materials are provided in Table 3A and 3B below. Alternatively, in further embodiments, the moderate volatile fragrance material can be present in an amount ranging from about 0 wt % to about 30 wt % of the fragrance component, about 1 wt % to about 30 wt %, about 1 wt % to about 29 wt %, or less than, equal to, or greater than about 0 wt %, 0.1, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.25, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt %. In still further embodiments, the moderate volatile fragrance material can be in an amount ranging from about 30 wt % to about 40 wt % of the fragrance component, about 32 wt % to about 35 wt %, less than, equal to, or greater than about 30 wt % 31, 32, 33, 34, 35, 36, 37, 38, 39, or 40 wt %. In some embodiments, the moderate volatile fragrance material can be the only fragrance material present. Relative to any other fragrance materials, the moderate volatile fragrance component can be present in a ratio ranging from about 20:1 to about 1:20, about 10:1 to about 1:10, about 5:1 to about 1:5, or about 1:1.

Preferable examples of moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. are provided in Table 3 Moderate Volatile Fragrance Materials. Preferably, the moderate volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, or at least 7 moderate volatile fragrance materials as disclosed in Table 3A. Natural fragrance materials or oils having an aggregate vapor pressure between 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. are provided in Table 3B. Moderate Volatile Natural Oils.

TABLE 3A Moderate Volatile Fragrance Materials Vaporat Pressure No. CAS Number IUPAC Name Common Name** (Torr at 25° C.)* 1. 24168-70-5 Pyrazine, 2- Methoxyisobutyl- 0.09950000 methoxy-3-(1- pyrazine methylpropyl)- 2. 89-79-2 Cyclohexanol, 5- Iso-Pulegol 0.09930000 methyl-2-(1- methylethenyl)-, (1R,2S,5R)- 3. 112-12-9 2-Undecanone Methyl Nonyl 0.09780000 Ketone 4. 103-05-9 Benzenepropanol, Phenyl Ethyl 0.09770000 α,α-dimethyl- Dimethyl Carbinol 5. 125-12-2 Bicyclo[2.2.1]heptan- Iso Bornyl 0.09590000 2-ol, 1,7,7- Acetate trimethyl-, 2-acetate, (1R,2R,4R)-rel- 6. 78-70-6 1,6-Octadien-3-ol, Linalool 0.09050000 3,7-dimethyl- 7. 101-97-3 Benzeneacetic acid, Ethyl Phenyl 0.08970000 ethyl ester Acetate 8. 100-86-7 Benzeneethanol, Dimethyl Benzyl 0.08880000 α,α-dimethyl- Carbinol 9. 188570-78-7 Cyclopropanecarboxylic Montaverdi 0.08640000 acid, (3Z)-3- hexen-1-yl ester 10. 67634-25-7 3-Cyclohexene-1- Floralate 0.08500000 methanol, 3,5- dimethyl-, 1-acetate 11. 112-44-7 Undecanal Undecyl 0.08320000 Aldehyde 12. 32669-00-4 Ethanone, 1-(3- Tanaisone ® 0.08150000 cycloocten-1-yl)- 13. 98-53-3 Cyclohexanone, 4- Patchi 0.07780000 (1,1-dimethylethyl)- 14. 35854-86-5 6-Nonen-1-ol, (6Z)- cis-6-None-1-ol 0.07770000 15. 5331-14-6 Benzene, (2- Butyl phenethyl 0.07760000 butoxyethyl)- ether 16. 80-57-9 Bicyclo[3.1.1]hept- Verbenone 0.07730000 3-en-2-one, 4,6,6- trimethyl- 17. 22471-55-2 Cyclohexanecarboxylic Thesaron 0.07670000 acid, 2,2,6- trimethyl-, ethyl ester, (1R,6S)-rel- 18. 60-12-8 Benzeneethanol Phenethyl alcohol 0.07410000 19. 106-26-3 2,6-Octadienal, 3,7- Neral 0.07120000 dimethyl-, (2Z)- 20. 5392-40-5 2,6-Octadienal, 3,7- Citral 0.07120000 dimethyl- 21. 89-48-5 Cyclohexanol, 5- Menthyl Acetate 0.07070000 methyl-2-(1- methylethyl)-, 1- acetate, (1R,2S,5R)- rel- 22. 119-36-8 Benzoic acid, 2- Methyl salicylate 0.07000000 hydroxy-, methyl ester 23. 104-46-1 Benzene, 1- Anethol 0.06870000 methoxy-4-(1E)-1- propen-1-yl- 24. 7549-37-3 2,6-Octadiene, 1,1- Citral Dimethyl 0.06780000 dimethoxy-3,7- Acetal dimethyl- 25. 25225-08-5 Cyclohexanemethanol Aphermate 0.06780000 α,3,3-trimethyl-, 1-formate 26. 3913-81-3 2-Decenal, (2E)- 2-Decene-1-al 0.06740000 27. 15373-31-6 3-Cyclopentene-1- Cantryl ® 0.06700000 acetonitrile, 2,2,3- trimethyl- 28. 6485-40-1 2-Cyclohexen-1-one, Laevo carvone 0.06560000 2-methyl-5-(1- methylethenyl)-, (5R)- 29. 16587-71-6 Cyclohexanone, 4- Orivone 0.06490000 (1,1- dimethylpropyl)- 30. 62406-73-9 6,10- Opalal CI 0.06290000 Dioxaspiro[4.5]decane, 8,8-dimethyl-7- (1-methylethyl)- 31. 3720-16-9 2-Cyclohexen-1-one, Livescone 0.06270000 3-methyl-5-propyl- 32. 13816-33-6 Benzonitrile, 4-(1- Cumin Nitrile 0.06230000 methylethyl)- 33. 67019-89-0 2,6-Nonadienenitrile Violet Nitrile 0.06200000 34. 53398-85-9 Butanoic acid, 2- cis-3-Hexenyl 0.06130000 methyl-, (3Z)-3- Alpha Methyl hexen-1-yl ester Butyrate 35. 208041-98-9 n/a Jasmonitrile 0.05920000 36. 16510-27-3 Benzene, 1- Toscanol 0.05870000 (cyclopropylmethyl)- 4-methoxy- 37. 111-80-8 2-Nonynoic acid, Methyl Octine 0.05680000 methyl ester Carbonate 38. 103-45-7 Acetic acid, 2- Phenyl Ethyl 0.05640000 phenylethyl ester Acetate 39. 2550-26-7 2-Butanone, 4- Benzyl Acetone 0.05570000 phenyl- 40. 13491-79-7 Cyclohexanol, 2- Verdol 0.05430000 (1,1-dimethylethyl)- 41. 7786-44-9 2,6-Nonadien-1-ol 2,6-Nonadien-1-ol 0.05370000 42. 103-28-6 Propanoic acid, 2- Benzyl Iso 0.05130000 methyl-, Butyrate phenylmethyl ester 43. 104-62-1 Formic acid, 2- Phenyl Ethyl 0.05050000 phenylethyl ester Formate 44. 28462-85-3 Bicyclo[2.2.1]heptan- Humus Ether 0.04870000 2-ol, 1,2,3,3- tetramethyl-, (1R,2R,4S)-rel- 45. 122-03-2 Benzaldehyde, 4-(1- Cuminic 0.04820000 methylethyl)- Aldehyde 46. 358331-95-0 2,5-Octadien-4-one, Pomarose 0.04810000 5,6,7-trimethyl-, (2E)- 47. 562-74-3 3-Cyclohexen-1-ol, Terpinenol-4 0.04780000 4-methyl-1-(1- methylethyl)- 48. 68527-77-5 3-Cyclohexene-1- Isocyclogeraniol 0.04640000 methanol, 2,4,6- trimethyl- 49. 35852-46-1 Pentanoic acid, (3Z)- Cis-3-Hexenyl 0.04580000 3-hexen-1-yl ester Valerate 50. 2756-56-1 Bicyclo[2.2.1]heptan- Iso Bornyl 0.04540000 2-ol, 1,7,7- Propionate trimethyl-, 2- propanoate, (1R,2R,4R)-rel- 51. 14374-92-6 Benzene, 1-methyl- Verdoracine 0.04460000 4-(1-methylethyl)-2- (1-propen-1-yl)- 52. 6784-13-0 3-Cyclohexene-1- Limonenal 0.04380000 propanal, β,4- dimethyl- 53. 8000-41-7 2-(4-methyl-1- Alpha Terpineol 0.04320000 cyclohex-3- enyl)propan-2-ol 54. 41884-28-0 1-Hexanol, 5- Tetrahydro 0.04230000 methyl-2-(1- Lavandulol methylethyl)-, (2R)- 55. 22457-23-4 3-Heptanone, 5- Stemone ® 0.04140000 methyl-, oxime 56. 104-50-7 2(3H)-Furanone, 5- Gamma 0.04080000 butyldihydro- Octalactone 57. 143-08-8 1-Nonanol Nonyl Alcohol 0.04070000 58. 3613-30-7 Octanal, 7-methoxy- Methoxycitronellal 0.04020000 3,7-dimethyl- 59. 67634-00-8 Acetic acid, 2-(3- Ally Amyl 0.04000000 methylbutoxy)-, 2- Glycolate propen-1-yl ester 60. 464-45-9 Bicyclo[2.2.1]heptan- 1-Borneol 0.03980000 2-ol, 1,7,7-trimethyl-, (1S,2R,4S)- 61. 124-76-5 Bicyclo[2.2.1]heptan- 1.7.7-Trimethyl- 0.03980000 2-ol, 1,7,7- Bicyclo-1.2.2- trimethyl-, Heptanol-2 (1R,2R,4R)-rel- 62. 67874-72-0 Cyclohexanol, 2- Coniferan 0.03980000 (1,1- dimethylpropyl)-, 1- acetate 63. 80-26-2 3-Cyclohexene-1- Terpinyl Acetate 0.03920000 methanol, α,α,4- trimethyl-, 1-acetate 64. 498-81-7 Cyclohexanemethanol, Dihydro 0.03920000 α,α,4-trimethyl- Terpineol 65. 112-45-8 10-Undecenal Undecylenic 0.03900000 aldehyde 66. 35044-57-6 2,4-Cyclohexadiene- Ethyl Safranate 0.03880000 1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester 67. 106-21-8 1-Octanol, 3,7- Dimethyl Octanol 0.03860000 dimethyl- 68. 84560-00-9 Cyclopentanol, 2- Cyclopentol 0.03790000 pentyl- 69. 82461-14-1 Furan, tetrahydro- Rhubafuran ® 0.03780000 2,4-dimethyl-4- phenyl- 70. 56011-02-0 Benzene, [2-(3- Phenyl Ethyl 0.03690000 methylbutoxy)ethyl]- Isoamyl Ether 71. 103-37-7 Butanoic acid, Benzyl Butyrate 0.03660000 phenylmethyl ester 72. 6378-65-0 Hexyl hexanoate Hexyl hexanoate 0.03490000 73. 118-61-6 Benzoic acid, 2- Ethyl salicylate 0.03480000 hydroxy-, ethyl ester 74. 98-52-2 Cyclohexanol, 4- Patchon 0.03480000 (1,1-dimethylethyl)- 75. 115-99-1 1,6-Octadien-3-ol, Linalyl Formate 0.03440000 3,7-dimethyl-, 3- formate 76. 112-54-9 Dodecanal Lauric Aldehyde 0.03440000 77. 53046-97-2 3,6-Nonadien-1-ol, 3,6-Nonadien-1-ol 0.03360000 (3Z,6Z)- 78. 76649-25-7 3,6-Nonadien-1-ol 3,6-Nonadien-1-ol 0.03360000 79. 141-25-3 3,7-Dimethyloct-6- Rhodinol 0.03290000 en-1-ol 80. 1975-78-6 Decanenitrile Decanonitrile 0.03250000 81. 2216-51-5 Cyclohexanol, 5- L-Menthol 0.03230000 methyl-2-(1- methylethyl)-, (1R,2S,5R)- 82. 3658-77-3 4-hydroxy-2,5- Pineapple Ketone 0.03200000 dimethylfuran-3-one 83. 103-93-5 Propanoic acid, 2- Para Cresyl iso- 0.03120000 methyl-, 4- Butyrate methylphenyl ester 84. 24717-86-0 Propanoic acid, 2- Abierate 0.03110000 methyl-, (1R,2S,4R)- 1,7,7-trimethylbicy- clo[2.2.1]hept- 2-yl ester, rel- 85. 67845-46-9 Acetaldehyde, 2-(4- Aldehyde XI 0.03090000 methylphenoxy)- 86. 67883-79-8 2-Butenoic acid, 2- Cis-3-Hexenyl 0.03060000 methyl-, (3Z)-3- Tiglate hexen-1-yl ester, (2E)- 87. 33885-51-7 Bicyclo[3.1.1]hept- Pino 0.03040000 2-ene-2-propanal, Acetaldehyde 6,6-dimethyl- 88. 105-85-1 6-Octen-1-ol, 3,7- Citronellyl 0.03000000 dimethyl-, 1-formate Formate 89. 70214-77-6 2-Nonanol, 6,8- Nonadyl 0.03010000 dimethyl- 90. 215231-33-7 Cyclohexanol, 1- Rossitol 0.02990000 methyl-3-(2- methylpropyl)- 91. 120-72-9 1H-Indole Indole 0.02980000 92. 2463-77-6 2-Undecenal 2-Undecene-1-al 0.02970000 93. 675-09-2 2H-Pyran-2-one, Levistamel 0.02940000 4,6-dimethyl- 94. 98-55-5 3-Cyclohexene-1- Alpha-Terpineol 0.02830000 methanol, α,α,4- trimethyl- 95. 81786-73-4 3-Hepten-2-one, Koavone 0.02750000 3,4,5,6,6- pentamethyl-, (3Z- 96. 122-97-4 Benzenepropanol Phenyl Propyl 0.02710000 Alcohol 97. 39212-23-2 2(3H)-Furanone, 5- Methyl 0.02700000 butyldihydro-4- Octalactone methyl- 98. 53767-93-4 7-Octen-2-ol, 2,6- Dihydro Terpinyl 0.02690000 dimethyl-, 2-acetate Acetate 99. 35044-59-8 1,3-Cyclohexadiene- Ethyl Safranate 0.02660000 1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester 100. 104-55-2 2-Propenal, 3- Cinnamic 0.02650000 phenyl- Aldehyde 101. 144-39-8 1,6-Octadien-3-ol, Linalyl 0.02630000 3,7-dimethyl-, 3- Propionate propanoate 102. 61931-80-4 1,6-Nonadien-3-ol, 3,7-Dimethyl-1,6- 0.02630000 3,7-dimethyl-, 3- nonadien-3-yl acetate acetate 103. 102-13-6 Benzeneacetic acid, Iso Butyl 0.02630000 2-methylpropyl ester Phenylacetate 104. 65443-14-3 Cyclopentanone, Veloutone 0.02610000 2,2,5-trimethyl-5- pentyl- 105. 141-12-8 2,6-Octadien-1-ol, Neryl Acetate 0.02560000 3,7-dimethyl-, 1- acetate, (2Z)- 106. 105-87-3 2,6-Octadien-1-ol, Geranyl acetate 0.02560000 3,7-dimethyl-, 1- acetate, (2E)- 107. 68141-17-3 Undecane, 1,1- Methyl Nonyl 0.02550000 dimethoxy-2- Acetaldehyde methyl- Dimethyl Acetal 108. 2206-94-2 Benzenemethanol, Indocolore 0.02550000 α-methylene-, 1- acetate 109. 10528-67-3 Cyclohexanepropanol, Cyclohexylmagnol 0.02550000 α-methyl- 110. 123-11-5 Benzaldehyde, 4- Anisic Aldehyde 0.02490000 methoxy- 111. 57576-09-7 Cyclohexanol, 5- Iso Pulegol 0.02480000 methyl-2-(1- Acetate methylethenyl)-, 1- acetate, (1R,2S,5R)- 112. 51566-62-2 6-Octenenitrile, 3,7- Citronellyl Nitrile 0.02470000 dimethyl- 113. 60335-71-9 2H-Pyran, 3,6- Rosyrane Super 0.02470000 dihydro-4-methyl-2- phenyl- 114. 30385-25-2 6-Octen-2-ol, 2,6- Dihydromyrcenol 0.02440000 dimethyl- 115. 101-84-8 Benzene, 1,1′- Diphenyl Oxide 0.02230000 oxybis- 116. 136-60-7 Benzoic acid, butyl Butyl Benzoate 0.02170000 ester 117. 93939-86-7 5,8-Methano-2H-1- Rhuboflor 0.02120000 benzopyran, 6- ethylideneoctahydro- 118. 83926-73-2 Cyclohexanepropanol, Coranol 0.02100000 α,α-dimethyl- 119. 125109-85-5 Benzenepropanal, β- Florhydral 0.02070000 methyl-3-(1- methylethyl)- 120. 104-21-2 Benzenemethanol, Anisyl Acetate 0.02050000 4-methoxy-, 1-acetate 121. 1365-19-1 2-Furanmethanol, 5- Linalool Oxide 0.02050000 ethenyltetrahydro- α,α,5-trimethyl- 122. 137-03-1 Cyclopentanone, 2- Frutalone 0.02040000 heptyl- 123. 2563-07-7 Phenol, 2-ethoxy-4- Ultravanil 0.02030000 methyl- 124. 1128-08-1 2-Cyclopenten-1- Dihydrojasmone 0.02020000 one, 3-methyl-2- pentyl- 125. 7493-57-4 Benzene, [2-(1- Acetaldehyde 0.01990000 propoxyethoxy)ethyl]- 126. 141-25-3 7-Octen-1-ol, 3,7- Rhodinol 0.01970000 dimethyl- 127. 216970-21-7 Bicyclo[4.3.1]decane, 3-Methoxy-7,7- 0.01960000 3-methoxy-7,7- dimethyl-10- dimethyl-10- methylenebicyclo methylene- [4.3.1.]decane 128. 319002-92-1 Propanoic acid, 2- Sclareolate ® 0.01960000 (1,1- dimethylpropoxy)-, propyl ester, (2S)- 129. 85-91-6 Benzoic acid, 2- Dimethyl 0.01930000 (methylamino)-, anthranilate methyl 130. 13828-37-0 Cyclohexanemethanol, Mayol 0.01920000 4-(1- methylethyl)-, cis- 131. 26330-65-4 (E)-6-ethyl-3- Super Muguet 0.01850000 methyloct-6-en-1-ol 132. 7540-51-4 6-Octen-1-ol, 3,7- L-Citronellol 0.01830000 dimethyl-, (3S)- 133. 106-22-9 6-Octen-1-ol, 3,7- Citronellol 0.01830000 dimethyl- 134. 543-39-5 7-Octen-2-ol, 2- Myrcenol 0.01820000 methyl-6-methylene- 135. 7775-00-0 Benzenepropanal, 4- Cyclemax 0.01820000 (1-methylethyl)- 136. 18479-54-4 4,6-Octadien-3-ol, Muguol 0.01800000 3,7-dimethyl- 137. 29214-60-6 Octanoic acid, 2- Gelsone 0.01790000 acetyl-, ethyl ester 138. 1209-61-6 5-Oxatricy- Tobacarol 0.01730000 clo[8.2.0.04,6]dodecane, 4,9,12,12- tetramethyl- 139. 57934-97-1 2-Cyclohexene-1- Givescone 0.01710000 carboxylic acid, 2- ethyl-6,6-dimethyl-, ethyl ester 140. 14901-07-6 3-Buten-2-one, 4- Beta-Ionone 0.01690000 (2,6,6-trimethyl-1- cyclohexen-1-yl)-, (3E)- 141. 64001-15-6 4,7-Methano-1H- Dihydro Cyclacet 0.01630000 inden-5-ol, octahydro-, 5-acetate 142. 95-41-0 2-Cyclopenten-1- Iso Jasmone T 0.01600000 one, 2-hexyl- 143. 134-20-3 Benzoic acid, 2- Methyl 0.01580000 amino-, methyl ester Anthranilate 144. 100-06-1 Ethanone, 1-(4- Para Methoxy 0.01550000 methoxyphenyl)- Acetophenone 145. 105-86-2 2,6-Octadien-1-ol, Geranyl Formate 0.01540000 3,7-dimethyl-, 1- formate, (2E)- 146. 154171-77-4 Spiro[1,3-dioxolane- Ysamber K ® 0.01470000 2,8′(5′H)-[2H- 2,4a]methanonaphthalene], hexahydro- 1′,1′,5′,5′- tetramethyl, (2′S,4′aS,8′aS)- (9CI) 147. 154171-76-3 Spiro[1,3-dioxolane- Ysamber 0.01470000 2,8′(5′H)-[2H- 2,4a]methanonaphthalene], 148. 127-41-3 3-Buten-2-one, 4- Alpha-Ionone 0.01440000 (2,6,6-trimethyl-2- cyclohexen-1-yl)-, (3E)- 149. 151-05-3 Benzeneethanol, Dimethyl Benzyl 0.01390000 α,α-dimethyl-, 1- Carbinyl Acetate acetate 150. 2500-83-6 4,7-Methano-1H- Flor Acetate 0.01370000 inden-5-ol, 3a,4,5,6,7,7a- hexahydro-, 5- acetate 151. 150-84-5 6-Octen-1-ol, 3,7- Citronellyl 0.01370000 dimethyl-, 1-acetate acetate 152. 30310-41-9 2H-Pyran, Pelargene 0.01350000 tetrahydro-2-methyl- 4-methylene-6- phenyl- 153. 68845-00-1 Bicyclo[3.3.1]nonane, Boisiris 0.01350000 2-ethoxy-2,6,6- trimethyl-9- methylene- 154. 106-24-1 2,6-Octadien-1-ol, Geraniol 0.01330000 3,7-dimethyl-, (2E)- 155. 106-25-2 2,6-Octadien-1-ol, Nerol 0.01330000 3,7-dimethyl-, (2Z)- 156. 75975-83-6 Bicyclo[7.2.0]undec- Vetyvenal 0.01280000 4-ene, 4,11,11- trimethyl-8- methylene-, (1R,4E,9S)- 157. 19870-74-7 1H-3a,7- Cedryl methyl 0.01280000 Methanoazulene, ether octahydro-6- methoxy-3,6,8,8- tetramethyl-, (3R,3aS,6S,7R,8aS)- 158. 87-44-5 Bicyclo[7.2.0]undec- Caryophyllene 0.01280000 4-ene, 4,11,11- Extra trimethyl-8- methylene-, (1R,4E,9S)- 159. 54440-17-4 1H-Inden-1-one, Safraleine 0.01260000 2,3-dihydro-2,3,3- trimethyl- 160. 110-98-5 2-Propanol, 1,1′- Dipropylene 0.01250000 oxybis- Glycol 161. 41890-92-0 2-Octanol, 7- Osyrol ® 0.01250000 methoxy-3,7- dimethyl- 162. 71077-31-1 4,9-Decadienal, 4,8- Floral Super 0.01230000 dimethyl- 163. 65-85-0 Benzoic Acid Benzoic Acid 0.01220000 164. 61444-38-0 3-Hexenoic acid, cis-3-hexenyl-cis- 0.01220000 (3Z)-3-hexen-1-yl 3-hexenoate ester, (3Z)- 165. 116044-44-1 Bicyclo[2.2.1]hept- Herbanate 0.01210000 5-ene-2-carboxylic acid, 3-(1- 166. 104-54-1 2-Propen-1-ol, 3- Cinnamic 0.01170000 phenyl- Alcohol 167. 78-35-3 Propanoic acid, 2- Linalyl 0.01170000 methyl-, 1-ethenyl- Isobutyrate 1,5-dimethyl-4- hexen-1-yl ester 168. 23495-12-7 Ethanol, 2-phenoxy-, Phenoxy Ethyl 0.01300000 1-propanoate Propionate 169. 103-26-4 2-Propenoic acid, 3- Methyl 0.01120000 phenyl-, methyl ester Cinnamate 170. 67634-14-4 Benzenepropanal, 2- Florazon (ortho- 0.01110000 ethyl-α,α-dimethyl- isomer) 171. 5454-19-3 Propanoic acid, N-Decyl 0.01100000 decyl ester Propionate 172. 93-16-3 Benzene, 1,2- Methyl Iso 0.01100000 dimethoxy-4-(1- Eugenol propen-1-yl)- 173. 81782-77-6 3-Decen-5-ol, 4- 4-Methyl-3- 0.01070000 methyl- decen-5-ol 174. 67845-30-1 Bicyclo[2.2.2]oct-5- Maceal 0.01060000 ene-2- carboxaldehyde, 6- methyl-8-(1- methylethyl)- 175. 97-53-0 Phenol, 2-methoxy- Eugenol 0.01040000 4-(2-propen-1-yl)- 176. 120-57-0 1,3-Benzodioxole-5- Heliotropin 0.01040000 carboxaldehyde 177. 93-04-9 Naphthalene, 2- Beta Naphthyl 0.01040000 methoxy- Methyl Ether Extra 99 178. 4826-62-4 2-Dodecenal 2 Dodecene-1-al 0.01020000 179. 20407-84-5 2-Dodecenal, (2E)- Aldehyde 0.01020000 Mandarin 180. 5462-06-6 Benzenepropanal, 4- Canthoxal 0.01020000 methoxy-α-methyl- 181. 94-60-0 1,4- Dimethyl 1,4- 0.01020000 Cyclohexanedicarboxylic cyclohexanedicarbox- acid, 1,4- ylate dimethyl ester 182. 57378-68-4 2-Buten-1-one, 1- delta-Damascone 0.01020000 (2,6,6-trimethyl-3- cyclohexen-1-yl)- 183. 17283-81-7 2-Butanone, 4- Dihydro Beta 0.01020000 (2,6,6-trimethyl-1- Ionone cyclohexen-1-yl)- 184. 1885-38-7 2-Propenenitrile, 3- Cinnamalva 0.01010000 phenyl-, (2E)- 185. 103-48-0 Propanoic acid, 2- Phenyl Ethyl Iso 0.00994000 methyl-, 2- Butyrate phenylethyl ester 186. 488-10-8 2-Cyclopenten-1- Cis Jasmone 0.00982000 one, 3-methyl-2- (2Z)-2-penten-1-yl- 187. 7492-67-3 Acetaldehyde, 2- Citronellyloxy- 0.00967000 [(3,7-dimethyl-6- acetaldehyde octen-1-yl)oxy]- 188. 68683-20-5 1-Cyclohexene-1- Iso Bergamate 0.00965000 ethanol, 4-(1- methylethyl)-, 1- formate 189. 3025-30-7 2,4-Decadienoic Ethyl 2,4- 0.00954000 acid, ethyl ester, Decadienoate (2E,4Z)- 190. 103-54-8 2-Propen-1-ol, 3- Cinnamyl Acetate 0.00940000 phenyl-, 1-acetate 191. 18127-01-0 Benzenepropanal, 4- Bourgeonal 0.00934000 (1,1-dimethylethyl)- 192. 3738-00-9 Naphtho[2,1- Ambrox ® or 0.00934000 b]furan, Cetalox ® or dodecahydro- Synambran 3a,6,6,9a- tetramethyl- 193. 51519-65-4 1,4- Tamisone 0.00932000 Methanonaphthalen- 5(1H)-one, 4,4a,7,8,8a- hexahydro- 194. 148-05-1 Dodecanoic acid, Dodecalactone 0.00931000 12-hydroxy-, λ- lactone (6CI,7CI); 1,12- 195. 6790-58-5 (3aR,5aS,9aS,9bR)- Ambronat ® or 0.00930000 3a,6,6,9a- Ambroxan ® tetramethyl- 2,4,5,5a,7,8,9,9b- octahydro-1H- benzo[e][1]benzofuran 196. 86-26-0 1,1′-Biphenyl, 2- Methyl Diphenyl 0.00928000 methoxy- Ether 197. 68738-94-3 2- Cyclomyral ® 0.00920000 Naphthalenecarbox- aldehyde, octahydro- 8,8-dimethyl 198. 2705-87-5 Cyclohexanepropanoic Allyl 0.00925000 acid, 2-propen-1- Cyclohexane yl ester Propionate 199. 7011-83-8 2(3H)-Furanone, 5- Lactojasmone ® 0.00885000 hexyldihydro-5- methyl- 200. 61792-11-8 2,6- Lemonile ® 0.00884000 Nonadienenitrile, 3,7-dimethyl- 201. 692-86-4 10-Undecenoic acid, Ethyl 0.00882000 ethyl ester Undecylenate 202. 103-95-7 Benzenepropanal, α- Cymal 0.00881000 methyl-4-(1- methylethyl)- 203. 13019-22-2 9-Decen-1-ol Rosalva 0.00879000 204. 94201-19-1 1- Methyl Laitone 0.00872000 Oxaspiro[4.5]decan- 10% TEC 2-one, 8-methyl- 205. 104-61-0 2(3H)-Furanone, γ-Nonalactone 0.00858000 dihydro-5-pentyl- 206. 706-14-9 2(3H)-Furanone, 5- γ-Decalactone 0.00852000 hexyldihydro- 207. 24720-09-0 2-Buten-1-one, 1- α-Damascone 0.00830000 (2,6,6-trimethyl-2- cyclohexen-1-yl)-, (2E)- 208. 39872-57-6 2-Buten-1-one, 1- Isodamascone 0.00830000 (2,4,4-trimethyl-2- cyclohexen-1-yl)-, (2E)- 209. 705-86-2 2H-Pyran-2-one, Decalactone 0.00825000 tetrahydro-6-pentyl- 210. 67634-15-5 Benzenepropanal, 4- Floralozone 0.00808000 ethyl-α,α-dimethyl - 211. 40527-42-2 1,3-Benzodioxole, 5- Heliotropin 0.00796000 (diethoxymethyl)- Diethyl Acetal 212. 56973-85-4 4-Penten-1-one, 1- Neobutenone α 0.00763000 (5,5-dimethyl-1- cyclohexen-1-yl)- 213. 128-51-8 Bicyclo[3.1.1]hept- Nopyl Acetate 0.00751000 2-ene-2-ethanol, 6,6- dimethyl-, 2-acetate 214. 103-36-6 2-Propenoic acid, 3- Ethyl Cinnamate 0.00729000 phenyl-, ethyl ester 215. 5182-36-5 1,3-Dioxane, 2,4,6- Floropal ® 0.00709000 trimethyl-4-phenyl- 216. 42604-12-6 Cyclododecane, Boisambrene 0.00686000 (methoxymethoxy)- 217. 33885-52-8 Bicyclo[3.1,1]hept- Pinyl Iso Butyrate 0.00685000 2-ene-2-propanal, Alpha α,α,6,6-tetramethyl- 218. 92015-65-1 2(3H)- Natactone 0.00680000 Benzofuranone, hexahydro-3,6- dimethyl- 219. 63767-86-2 Cyclohexanemethanol Mugetanol 0.00678000 α-methyl-4-(1- methylethyl)- 220. 3288-99-1 Benzeneacetonitrille, Marenil CI 0.00665000 4-(1,1- dimethylethyl)- 221. 35044-68-9 2-Buten-1-one, 1- beta-Damascone 0.00655000 (2,6,6-trimethyl-1- cyclohexen-1-yl)- 222. 41724-19-0 1,4- Plicatone 0.00652000 Methanonaphthalen- 6(2H)-one, octahydro-7-methyl 223. 75147-23-8 Bicyclo[3.2,1]octan- Buccoxime ® 0.00647000 8-one, 1,5-dimethyl-, oxime 224. 25634-93-9 2-Methyl-5- Rosaphen ® 0.00637000 phenylpentan-1-ol 600064 225. 55066-48-3 3-Methyl-5- Phenyl Hexanol 0.00637000 phenylpentanol 226. 495-62-5 Cyclohexene, 4-(1,5- Bisabolene 0.00630000 dimethyl-4-hexen-1- ylidene)-1-methyl- 227. 2785-87-7 Phenol, 2-methoxy- Dihydro Eugenol 0.00624000 4-propyl- 228. 87-19-4 Benzoic acid, 2- Iso Butyl 0.00613000 hydroxy-, 2- Salicylate methylpropyl ester 229. 4430-31-3 2H-1-Benzopyran-2- Octahydro 0.00586000 one, octahydro- Coumarin 230. 38462-22-5 Cyclohexanone, 2- Ringonol 50 TEC 0.00585000 (1-mercapto-1- methylethyl)-5- methyl- 231. 77-83-8 2-Oxiranecarboxylic Ethyl Methyl 0.00571000 acid, 3-methyl-3- Phenyl Glycidate phenyl-, ethyl ester 232. 37677-14-8 3-Cyclohexene-1- Iso Hexenyl 0.00565000 carboxaldehyde, 4- Cyclohexenyl (4-methyl-3-penten- Carboxaldehyde 1-yl)- 233. 103-60-6 Propanoic acid, 2- Phenoxy Ethyl 0.00562000 methyl-, 2- iso-Butyrate phenoxyethyl ester 234. 18096-62-3 Indeno[1,2-d]-1,3- Indoflor ® 0.00557000 dioxin, 4,4a,5,9b- tetrahydro- 235. 63500-71-0 2H-Pyran-4-ol, Florosa Q/Florol 0.00557000 tetrahydro-4-methyl- 2-(2-methylpropyl)- 236. 65405-84-7 Cyclohexanebutanal, Cetonal ® 0.00533000 α,2,6,6-tetramethyl- 237. 171102-41-3 4,7-Methano-1H- Flor Acetate 0.00530000 inden-6-ol, 3a,4,5,6,7,7a- hexahydro-8,8- dimethyl-, 6-acetate 238. 10339-55-6 1,6-Nonadien-3-ol, Ethyl linalool 0.00520000 3,7-dimethyl- 239. 23267-57-4 3-Buten-2-one, 4- Ionone Epoxide 0.00520000 (2,2,6-trimethyl-7- Beta oxabicyclo[4.1.0]hept- 1-yl)- 240. 97-54-1 Phenol, 2-methoxy- Isoeugenol 0.00519000 4-(1-propen-1-yl)- 241. 67663-01-8 2(3H)-Furanone, 5- Peacholide 0.00512000 hexyldihydro-4- methyl- 242. 33885-52-8 Bicyclo[3.1.1]hept- Pinyl Iso Butyrate 0.00512000 2-ene-2-propanal, Alpha α,α,6,6-tetramethyl- 243. 23696-85-7 2-Buten-1-one, 1- Damascenone 0.00503000 (2,6,6-trimethyl-1,3- cyclohexadien-1-yl)- 244. 80-71-7 2-Cyclopenten-1- Maple Lactone 0.00484000 one, 2-hydroxy-3- methyl- 245. 67662-96-8 Propanoic acid, 2,2- Pivarose Q 0.00484000 dimethyl-, 2- phenylethyl ester 246. 2437-25-4 Dodecanenitrile Clonal 0.00480000 247. 141-14-0 6-Octen-1-ol, 3,7- Citronellyl 0.00469000 dimethyl-, 1- Propionate propanoate 248. 54992-90-4 3-Buten-2-one, 4- Myrrhone 0.00460000 (2,2,3,6- tetramethylcyclohexyl)- 249. 55066-49-4 Benzenepentanal, β- Mefranal 0.00455000 methyl- 250. 7493-74-5 Acetic acid, 2- Allyl Phenoxy 0.00454000 phenoxy-, 2-propen- Acetate 1-yl ester 251. 80-54-6 Benzenepropanal, 4- Lilial ® 0.00444000 (1,1-dimethylethyl)- α-methyl- 252. 86803-90-9 4,7-Methano-1H- Scentenal ® 0.00439000 indene-2- carboxaldehyde, octahydro-5- methoxy- 253. 68991-97-9 2-Naphtha- Melafleur 0.00436000 lenecarboxaldehyde, 1,2,3,4,5,6,7,8- octahydro-8,8- dimethyl- 254. 18871-14-2 Pentitol, 1,5- Jasmal 0.00434000 anhydro-2,4- dideoxy-2-pentyl-, 3-acetate 255. 58567-11-6 Cyclododecane, Boisambren Forte 0.00433000 (ethoxymethoxy)- 256. 94400-98-3 Naphth[2,3- Molaxone 0.00425000 b]oxirene, 1a,2,3,4,5,6,7,7a- octahydro- 1a,3,3,4,6,6- hexamethyl-, (1aR,4S,7aS)-rel- 257. 79-69-6 3-Buten-2-one, 4- alpha-Irone 0.00419000 (2,5,6,6-tetramethyl- 2-cyclohexen-1-yl)- 258. 65442-31-1 Quinoline, 6-(1- Iso Butyl 0.00408000 methylpropyl)- Quinoline 259. 87731-18-8 Carbonic acid, 4- Violiff 0.00401000 cycloocten-1-yl methyl ester 260. 173445-65-3 1H-Indene-5- Hivernal (A- 0.00392000 propanal, 2,3- isomer) dihydro-3,3- dimethyl- 261. 23911-56-0 Ethanone, 1-(3- Nerolione 0.00383000 methyl-2- benzofuranyl)- 262. 52474-60-9 3-Cyclohexene-1- Precyclemone B 0.00381000 carboxaldehyde, 1- methyl-3-(4-methyl- 3-penten-1-yl)- 263. 139539-66-5 6-Oxabicyclo Cassifix 0.00381000 [3.2.1]octane, 5- methyl-1-(2,2,3- trimethyl-3- cyclopenten-1-yl)- 264. 80858-47-5 Benzene, [2- Phenafleur 0.00380000 (cyclohexyloxy)ethyl]- 265. 32764-98-0 2H-Pyran-2-one, Jasmolactone 0.00355000 tetrahydro-6-(3- penten-1-yl)- 266. 78417-28-4 2,4,7-Decatrienoic Ethyl 2,4,7- 0.00353000 acid, ethyl ester decatrienoate 267. 140-26-1 Butanoic acid, 3- Beta Phenyl Ethyl 0.00347000 methyl-, 2- Isovalerate phenylethyl ester 268. 105-90-8 2,6-Octadien-1-ol, Geranyl 0.003360000 3,7-dimethyl-, 1- Propionate propanoate, (2E)- 269. 41816-03-9 Spiro[1,4- Rhubofix ® 0.00332000 methanonaphthalene- 2(1H),2′-oxirane], 3,4,4a,5,8,8a- hexahydro-3′,7- dimethyl- 270. 7070-15-7 Ethanol, 2- Arbanol 0.00326000 [[(1R,2R,4R)- 1,7,7-trimethylbicy- clo[2.2.1]hept- 2-yl]oxy]-, rel- 271. 93-29-8 Phenol, 2-methoxy- Iso Eugenol 0.00324000 4-(1-propen-1-yl)-, Acetate 1-acetate 272. 476332-65-7 2H-Indeno[4,5- Amber Xtreme 0.00323000 b]furan, decahydro- Compound 1 2,2,6,6,7,8,8- heptamethyl- 273. 68901-15-5 Acetic acid, 2- Cyclogalbanate 0.00323000 (cyclohexyloxy)-, 2- propen-1-yl ester 274. 107-75-5 Octanal, 7-hydroxy- Hydroxycitronellal 0.00318000 3,7-dimethyl- 275. 68611-23-4 Naphtho[2,1- Grisalva 0.00305000 b]furan, 9b- ethyldodecahydro- 3a,7,7-trimethyl- 276. 313973-37-4 1,6-Heptadien-3- Pharaone 0.00298000 one, 2-cyclohexyl- 277. 137-00-8 5-Thiazoleethanol, Sulfurol 0.00297000 4-methyl- 278. 7779-30-8 1-Penten-3-one, 1- Methyl Ionone 0.00286000 (2,6,6-trimethyl-2- cyclohexen-1-yl)- 279. 127-51-5 3-Buten-2-one, 3- Isoraldeine Pure 0.00282000 methyl-4-(2,6,6- trimethyl-2- cyclohexen-1-yl)- 280. 72903-27-6 1,4- Fructalate ™ 0.00274000 Cyclohexanedicarboxylic acid, 1,4- diethyl ester 281. 7388-22-9 3-Buten-2-one, 4- Ionone Gamma 0.00272000 (2,2-dimethyl-6- Methyl methylenecyclohexyl)- 3-methyl- 282. 104-67-6 2(3H)-Furanone, 5- gamma- 0.00271000 heptyldihydro- Undecalactone (racemic) 283. 1205-17-0 1,3-Benzodioxole-5- Helional 0.00270000 propanal, α-methyl- 284. 33704-61-9 4H-Inden-4-one, Cashmeran 0.00269000 1,2,3,5,6,7- hexahydro-1,1,2,3,3- pentamethyl- 285. 36306-87-3 Cyclohexanone, 4- Kephalis 0.00269000 (1-ethoxyethenyl)- 3,3,5,5-tetramethyl- 286. 97384-48-0 Benzenepropanenitrile, Citrowanil ® B 0.00265000 α-ethenyl-α- methyl- 287. 141-13-9 9-Undecenal, 2,6,10- Adoxal 0.00257000 trimethyl- 288. 2110-18-1 Pyridine, 2-(3- Corps Racine VS 0.00257000 phenylpropyl)- 289. 27606-09-3 Indeno[1,2-d]-1,3- Magnolan 0.00251000 dioxin, 4,4a,5,9b- tetrahydro-2,4- dimethyl- 290. 67634-20-2 Propanoic acid, 2- Cyclabute 0.00244000 methyl-, 3a,4,5,6,7,7a- hexahydro-4,7- methano-1H-inden- 5-yl ester 291. 65405-72-3 1-Naphthalenol, Oxyoctaline 0.00236000 1,2,3,4,4a,7,8,8a- Formate octahydro-2,4a,5,8a- tetramethyl-, 1- formate 292. 122-40-7 Heptanal, 2- Amyl Cinnamic 0.00233000 (phenylmethylene)- Aldehyde 293. 103694-68-4 Benzenepropanol, Majantol ® 0.00224000 β,β,3-trimethyl- 294. 13215-88-8 2-Cyclohexene-1-one, Tabanone Coeur 0.00223000 4-(2-buten-1- ylidene)-3,5,5- trimethyl- 295. 25152-85-6 3-Hexen-1-ol, 1- Cis-3-Hexenyl 0.00203000 benzoate, (3Z)- Benzoate 296. 406488-30-0 2-Ethyl-N-methyl-N- Paradisamide 0.00200000 (m-tolyl)butanamide 297. 121-33-5 Benzaldehyde, 4- Vanillin 0.00194000 hydroxy-3-methoxy- 298. 77-54-3 1H-3a,7- Cedac 0.00192000 Methanoazulen-6-ol, octahydro-3,6,8,8- tetramethyl-, 6- acetate, (3R,3aS,6R,7R,8aS)- 299. 76842-49-4 4,7-Methano-1H- Frutene 0.00184000 inden-6-ol, 3a,4,5,6,7,7a- hexahydro-8,8- dimethyl-, 6- propanoate 300. 121-39-1 2-Oxiranecarboxylic Ethyl Phenyl 0.00184000 acid, 3-phenyl-, Glycidate ethyl ester 301. 211299-54-6 4H-4a,9- Ambrocenide ® 0.00182000 Methanoazuleno[5,6- d]-1,3-dioxole, octahydro- 2,2,5,8,8,9a- hexamethyl-, (4aR,5R,7aS,9R)- 302. 285977-85-7 (2,5-Dimethyl-1,3- Lilyflore 0.00180000 dihydroinden-2- yl)methanol 303. 10094-34-5 Butanoic acid, 1,1- Dimethyl Benzyl 0.00168000 dimethyl-2- Carbinyl Butyrate phenylethyl ester 304. 40785-62-4 Cyclododeca[c] Muscogene 0.00163000 furan, 1,3,3a,4,5,6,7, 8,9,10,11,13a- dodecahydro- 305. 75490-39-0 Benzenebutanenitrile, Khusinil 0.00162000 α,α,γ-trimethyl- 306. 55418-52-5 2-Butanone, 4-(1,3- Dulcinyl 0.00161000 benzodioxol-5-yl)- 307. 3943-74-6 Benzoic acid, 4- Carnaline 0.00157000 hydroxy-3-methoxy-, methyl ester 308. 72089-08-8 3-Cyclopentene-1- Brahmanol ® 0.00154000 butanol, β,2,2,3- tetramethyl-2- Methyl-4-(2,2,3- trimethyl-3- cyclopenten-1- yl)butanol 309. 3155-71-3 2-Butenal, 2-methyl- Boronal 0.00147000 4-(2,6,6-trimethyl-1- cyclohexen-1-yl)- 310. 2050-08-0 Benzoic acid, 2- Amyl Salicylate 0.00144000 hydroxy-, pentyl ester 311. 41199-20-6 2-Naphthalenol, Ambrinol 0.00140000 decahydro-2,5,5- trimethyl- 312. 12262-03-2 ndecanoic acid, 3- Iso Amyl 0.00140000 methylbutyl ester Undecylenate 313. 107-74-4 1,7-Octanediol, 3,7- Hydroxyol 0.00139000 dimethyl- 314. 91-64-5 2H-1-Benzopyran-2- Coumarin 0.00130000 one 315. 68901-32-6 1,3-Dioxolane, 2-[6- Glycolierral 0.00121000 methyl-8-(1- methylethyl)bicy- clo[2.2,2]oct-5- en-2-yl]- 316. 68039-44-1 Propanoic acid, 2,2- Pivacyclene 0.00119000 dimethyl-, 3a,4,5,6, 7,7a-hexahydro-4,7- methano-1H-inden- 6-yl ester 317. 106-29-6 Butanoic acid, (2E)- Geranyl Butyrate 0.00116000 3,7-dimethyl-2,6- octadien-1-yl ester 318. 5471-51-2 2-Butanone, 4-(4- Raspberry ketone 0.00106000 hydroxyphenyl)- 319. 109-42-2 10-Undecenoic acid, Butyl 0.00104000 butyl ester Undecylenate 320. 2785-89-9 4-Ethyl-2- 4-Ethylguaiacol 0.02000000 methoxyphenol 321. 27538-10-9 2-ethyl-4-hydroxy- Homofuronol 0.01210000 5-methylfuran-3-one *Vapor Pressures are acquired as described in the Test Methods Section. **Origin: Same as for Table 2 hereinabove.

TABLE 3B Moderate Volatile Natural Oils. No. Natural oil Supplier 1. Bay Oil Terpeneless IFF 2. Cade Oil H. Reynaud & Fils 3. Cedar Atlas Oil Robertet 4. Cinnamon Bark Oil Robertet 5. Cinnamon Oleoresin Citrus & Allied Essences 6. Clove Bud Oil Robertet 7. Clove Leaf Oil Rectified H. Reynaud & Fils 8. Clove Stem Oil H. Reynaud & Fils 9. Davana Oil Robertet 10. Geranium Bourbon Robertet 11. Ginger Oil Fresh Madagascar IFF 12. Hay Absolute MD 50 PCT IFF 13. Juniperberry Oil T'less Robertet 14. Papyrus Oil Robertet 15. Rose Absolute Oil Robertet 16. Tonka Bean Absolute Robertet 17. Wormwood Oil Robertet

Suppliers: Citrus & Allied Essences, New York, USAH. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, N.J., USA Robertet, Grasse, France

Moderate volatile fragrance materials can be selected from the group of Tables 3A or 3B. However, it is understood by one skilled in the art that other moderate volatile fragrance materials, not recited in Tables 3A or 3B, would also fall within the scope of the present invention, so long as they have a vapor pressure of 0.1 to 0.001 Torr at 25° C.

High Volatile Fragrance Materials

The fragrance component includes at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. In some examples, the high volatile fragrance material can include at least 2 high volatile fragrance materials, 3 high volatile fragrance materials, or at least 5 high volatile fragrance materials, or at least 7 high volatile fragrance materials. In some embodiments, the high volatile fragrance component can be in a range of from about 0 wt % to about 100 wt % of the fragrance component, about 10 wt % to about 90 wt %, about 20 wt % to about 80 wt %, about 30 wt % to about 70 wt %, or about 40 wt % to about 60 wt %. The exact wt % of the high volatile fragrance component can vary greatly based on the fragrance's construction. For example, in some examples, where the high volatile fragrance material is present in a top-heavy construction, the high volatile fragrance material can be greater than about 30 wt % of the fragrance component, greater than about 40 wt %, greater than about 50 wt %, greater than about 60 wt %, about 31 wt % to about 60 wt %, about 40 wt % to about 50 wt %, or less than, equal to, or greater than about 30 wt %, 31, 35, 40, 45, 50, 55, 60, 65, 70, or 75 wt %. In some other examples, the high volatile fragrance material can be present in an amount ranging from about 0 wt % to about 30 wt % of the fragrance component, about 1 wt % to about 30 wt %, about 5 wt % to about 30 wt %, or less than, equal to, or greater than about 0 wt %, 0.1, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.25, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt %. In still further embodiments, the high volatile fragrance material can be in an amount ranging from about 30 wt % to about 40 wt % of the fragrance component, about 32 wt % to about 35 wt %, less than, equal to, or greater than about 30 wt % 31, 32, 33, 34, 35, 36, 37, 38, 39, or 40 wt %. In some embodiments, the low-volatile fragrance material can be the only fragrance material present. If there are more than one high volatile fragrance materials, then the ranges provided hereinabove cover the total of all of the high volatile fragrance materials. Suitable examples of high volatile fragrances materials are provided in Tables 4A and 4B below. Relative to any other fragrance materials, the high volatile fragrance component can be present in a ratio ranging from about 20:1 to about 1:20, about 10:1 to about 1:10, about 5:1 to about 1:5, or about 1:1.

Preferably, the high volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7 materials, or at least 9 high volatile fragrance materials as disclosed in Table 4A. Natural fragrance materials or oils having an aggregate vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. are provided in Table 4B. High Volatile Natural Oils.

TABLE 4A High Volatile Fragrance Materials Vapor Pressure No. CAS Number IUPAC Name Common Name** (Torr at 25° C.)* 1. 107-31-3 Formic acid, Methyl Formate 732.00000000 methyl ester 2. 75-18-3 Methane, 1,1′- Dimethyl Sulfide 647.00000000 thiobis- 1.0% In DEP 3. 141-78-6 Acetic acid ethyl Ethyl Acetate 112.00000000 ester 4. 105-37-3 Propanoic acid, Ethyl Propionate 44.50000000 ethyl ester 5. 110-19-0 Acetic acid, 2- Isobutyl Acetate 18.00000000 methylpropyl ester 6. 105-54-4 Butanoic acid, Ethyl Butyrate 13.90000000 ethyl ester 7. 14765-30-1 1-Butanol Butyl Alcohol 8.52000000 8. 7452-79-1 Butanoic acid, 2- Ethyl-2-Methyl 7.85000000 methyl-, ethyl Butyrate ester 9. 123-92-2 1-Butanol, 3- Iso Amyl Acetate 5.68000000 methyl-, 1- acetate 10. 66576-71-4 Butanoic acid, 2- Iso Propyl 2- 5.10000000 methyl-, 1- Methylbutyrate methylethyl ester 11. 110-43-0 2-Heptanone Methyl Amyl 4.73000000 Ketone 12. 6728-26-3 2-Hexenal, (2E)- Trans-2 Hexenal 4.62000000 13. 123-51-3 1-Butanol, 3- Isoamyl Alcohol 4.16000000 methyl- 14. 1191-16-8 2-Buten-1-ol, 3- Prenyl acetate 3.99000000 methyl-, 1- acetate 15. 57366-77-5 1,3-Dioxolane-2- Methyl Dioxolan 3.88000000 methanamine, N- methyl- 16. 7785-70-8 Bicyclo[3.1.1]hept- Alpha Pinene 3.49000000 2-ene, 2,6,6- trimethyl-, (1R,5R)- 17. 79-92-5 Bicyclo[2.2.1]heptane, Camphene 3.38000000 2,2-dimethyl-3- methylene- 18. 94087-83-9 2-Butanethiol, 4- 4-Methoxy-2- 3.31000000 methoxy-2- Methyl-2- methyl- Butanenthiol 19. 39255-32-8 Pentanoic acid, Manzanate 2.91000000 2-methyl-, ethyl ester 20. 3387-41-5 Bicyclo[3.1.0]hexane, Sabinene 2.63000000 4-methylene-1-(1- methylethyl)- 21. 127-91-3 Bicyclo[3.1.1]heptane, Beta Pinene 2.40000000 6,6-dimethyl-2- methylene- 22. 105-68-0 1-Butanol, 3- Amyl Propionate 2.36000000 methyl-, 1- propanoate 23. 123-35-3 1,6-Octadiene, 7- Myrcene 2.29000000 methyl-3- methylene- 24. 124-13-0 Octanal Octyl Aldehyde 2.07000000 25. 7392-19-0 2H-Pyran, 2- Limetol 1.90000000 ethenyltetrahydro- 2,6,6-trimethyl- 26. 111-13-7 2-Octanone Methyl Hexyl 1.72000000 Ketone 27. 123-66-0 Hexanoic acid, Ethyl Caproate 1.66000000 ethyl ester 28. 470-82-6 2- Eucalyptol 1.65000000 Oxabicyclo[2.2.2]octane, 1,3,3-trimethyl- 29. 99-87-6 Benzene, 1- Para Cymene 1.65000000 methyl-4-(1- methylethyl)- 30. 104-93-8 Benzene, 1- Para Cresyl Methyl 1.65000000 methoxy-4- Ether methyl- 31. 13877-91-3 1,3,6-Octatriene, Ocimene 1.56000000 3,7-dimethyl- 32. 138-86-3 Cyclohexene, 1- dl-Limonene 1.54000000 methyl-4-(1- methylethenyl)- 33. 5989-27-5 Cyclohexene, 1- d-limonene 1.54000000 methyl-4-(1- methylethenyl)-, (4R)- 34. 106-68-3 3-Octanone Ethyl Amyl Ketone 1.50000000 35. 110-41-8 Undecanal, 2- Methyl Nonyl 1.43000000 methyl- Acetaldehyde 36. 142-92-7 Acetic acid, Hexyl acetate 1.39000000 hexyl ester 37. 110-93-0 5-Hepten-2-one, Methyl Heptenone 1.28000000 6-methyl- 38. 81925-81-7 2-Hepten-4-one, Filbertone 1% in 1.25000000 5-methyl- TEC 39. 3681-71-8 3-Hexen-1-ol, 1- cis-3-Hexenyl 1.22000000 acetate, (3Z)- acetate 40. 97-64-3 Propanoic acid, Ethyl Lactate 1.16000000 2-hydroxy-, ethyl ester 41. 586-62-9 Cyclohexene, Terpineolene 1.13000000 1-methyl-4-(1- methylethylidene)- 42. 51115-64-1 Butanoic acid, 2- Amyl butyrate 1.09000000 methylbutyl ester 43. 106-27-4 Butanoic acid, 3- Amyl Butyrate 1.09000000 methylbutyl ester 44. 99-85-4 1,4-Cyclohexadiene, Gamma Terpinene 1.08000000 1-methyl-4-(1- methylethyl)- 45. 18640-74-9 Thiazole, 2-(2- 2-Isobutylthiazole 1.07000000 methylpropyl)- 46. 928-96-1 3-Hexen-1-ol, cis-3-Hexenol 1.04000000 (3Z)- 47. 100-52-7 Benzaldehyde Benzaldehyde 0.97400000 48. 141-97-9 Butanoic acid, 3- Ethyl Acetoacetate 0.89000000 oxo-, ethyl ester 49. 928-95-0 2-Hexen-1-ol, Trans-2-Hexenol 0.87300000 (2E)- 50. 928-94-9 2-Hexen-1-ol, Beta Gamma 0.87300000 (2Z)- Hexenol 51. 24691-15-4 Cyclohexane, 3- Herbavert 0.85200000 ethoxy-1,1,5- trimethyl-, cis- (9CI) 52. 19872-52-7 2-Pentanone, 4- 4-Methyl-4- 0.84300000 mercapto-4- Mercaptopentan-2- methyl- one 1 ppm TEC 53. 3016-19-1 2,4,6-Octatriene, Allo-Ocimene 0.81600000 2,6-dimethyl-, (4E,6E)- 54. 69103-20-4 Oxirane, 2,2- Myroxide 0.80600000 dimethyl-3-(3- methyl-2,4- pentadien-1-yl)- 55. 189440-77-5 4,7-Octadienoic Anapear 0.77700000 acid, methyl ester, (4E)- 56. 67633-96-9 Carbonic acid, Liffarome ™ 0.72100000 (3Z)-3-hexen-1- yl methyl ester 57. 123-68-2 Hexanoic acid, Allyl Caproate 0.67800000 2-propen-1-yl ester 58. 106-72-9 5-Heptenal, 2,6- Melonal 0.62200000 dimethyl- 59. 106-30-9 Heptanoic acid, Ethyl Oenanthate 0.60200000 ethyl ester 60. 68039-49-6 3-Cyclohexene-1- Ligustral or Triplal 0.57800000 carboxaldehyde, 2,4-dimethyl- 61. 101-48-4 Benzene, (2,2- Phenyl 0.55600000 dimethoxyethyl)- Acetaldehyde Dimethyl Acetal 62. 16409-43-1 2H-Pyran, Rose Oxide 0.55100000 tetrahydro-4- methyl-2-(2- methyl-1- propen-1-yl)- 63. 925-78-0 3-Nonanone Ethyl Hexyl Ketone 0.55100000 64. 100-47-0 Benzonitrile Benzyl Nitrile 0.52400000 65. 589-98-0 3-Octanol Octanol-3 0.51200000 66. 58430-94-7 1-Hexanol, Iso Nonyl Acetate 0.47000000 3,5,5-trimethyl-, 1-acetate 67. 10250-45-0 4-Heptanol, Alicate 0.45400000 2,6-dimethyl-, 4-acetate 68. 105-79-3 Hexanoic acid, Iso Butyl Caproate 0.41300000 2-methylpropyl ester 69. 2349-07-7 Propanoic acid, Hexyl isobutyrate 0.41300000 2-methyl-, hexyl ester 70. 23250-42-2 Cyclohexanecar- Cyprissate 0.40500000 boxylic acid, 1,4- dimethyl-, methyl ester, trans- 71. 122-78-1 Benzeneacetaldehyde Phenyl acetaldehyde 0.36800000 72. 5405-41-4 Butanoic acid, 3- Ethyl-3-Hydroxy 0.36200000 hydroxy-, ethyl Butyrate ester 73. 105-51-3 Propanedioic Diethyl Malonate 0.34400000 acid, 1,3-diethyl ester 74. 93-58-3 Benzoic acid, Methyl Benzoate 0.34000000 methyl ester 75. 16356-11-9 1,3,5- Undecatriene 0.33600000 Undecatriene 76. 65405-70-1 4-Decenal, (4E)- Decenal (Trans-4) 0.33100000 77. 54546-26-8 1,3-Dioxane, 2- Herboxane 0.33000000 butyl-4,4,6- trimethyl- 78. 13254-34-7 2-Heptanol, 2,6- Dimethyl-2 6- 0.33000000 dimethyl- Heptan-2-ol 79. 98-86-2 Ethanone, 1- Acetophenone 0.29900000 phenyl- 80. 93-53-8 Benzeneacetaldehyde, Hydratropic 0.29400000 α-methyl- aldehyde 81. 80118-06-5 Propanoic acid, Iso Pentyrate 0.28500000 2-methyl-, 1,3- dimethyl-3- buten-1-yl ester 82. 557-48-2 2,6-Nonadienal, E Z-2,6-Nonadien- 0.28000000 (2E,6Z)- 1-al 83. 24683-00-9 Pyrazine, 2- 2-Methoxy-3- 0.27300000 methoxy-3-(2- Isobutyl Pyrazine methylpropyl)- 84. 104-57-4 Formic acid, Benzyl Formate 0.27300000 phenylmethyl ester 85. 104-45-0 Benzene, 1- Dihydroanethole 0.26600000 methoxy-4- propyl- 86. 491-07-6 Cyclohexanone, Iso Menthone 0.25600000 5-methyl-2-(1- methylethyl)-, (2R,5R)-rel- 87. 89-80-5 Cyclohexanone, Menthone Racemic 0.25600000 5-methyl-2-(1- methylethyl)-, (2R,5S)-rel- 88. 2463-53-8 2-Nonenal 2 Nonen-1-al 0.25600000 89. 55739-89-4 Cyclohexanone, Thuyacetone 0.25000000 2-ethyl-4,4- dimethyl- 90. 150-78-7 Benzene, 1,4- Hydroquinone 0.25000000 dimethoxy- Dimethyl Ether 91. 64988-06-3 Benzene, 1- Rosacene 0.24600000 (ethoxymethyl)- 2-methoxy- 92. 76-22-2 Bicyclo[2,2.1]heptan- Camphor gum 0.22500000 2-one, 1,7,7-trimethyl- 93. 67674-46-8 2-Hexene, 6,6- Methyl 0.21400000 dimethoxy-2,5,5- Pamplemousse trimethyl- 94. 112-31-2 Decanal Decyl Aldehyde 0.20700000 95. 16251-77-7 Benzenepropanal, Trifernal 0.20600000 β-methyl- 96. 93-92-5 Benzenemethanol, Methylphenyl- 0.20300000 α-methyl-, 1- carbinol Acetate acetate 97. 143-13-5 Acetic acid, Nonyl Acetate 0.19700000 nonyl ester 98. 122-00-9 Ethanone, 1-(4- Para Methyl 0.18700000 methylphenyl)- Acetophenone 99. 24237-00-1 2H-Pyran, 6- Gyrane 0.18600000 butyl-3,6- dihydro-2,4- dimethyl- 100. 41519-23-7 Propanoic acid, Hexenyl 0.18200000 2-methyl-, (3Z)- Isobutyrate 3-hexen-1-yl ester 101. 93-89-0 Benzoic acid, Ethyl Benzoate 0.18000000 ethyl ester 102. 20780-48-7 3-Octanol, 3,7- Tetrahydro Linalyl 0.18000000 dimethyl-, 3- Acetate acetate 103. 101-41-7 Methyl 2- Methylphenyl 0.17600000 phenylacetate acetate 104. 40853-55-2 1-Hexanol, 5- Tetrahydro 0.17300000 methyl-2-(1- Lavandulyl methylethyl)-, 1- Acetate acetate 105. 933-48-2 Cyclohexanol, Trimethylcyclo- 0.17300000 3,3,5-trimethyl-, hexanol (1R,5R)-rel- 106. 35158-25-9 2-Hexenal, 5- Lactone of Cis 0.17200000 methyl-2-(1- Jasmone methylethyl)- 107. 18479-58-8 7-Octen-2-ol, Dihydromyrcenol 0.16600000 2,6-dimethyl- 108. 140-11-4 Acetic acid, Benzyl acetate 0.16400000 phenylmethyl ester 109. 14765-30-1 Cyclohexanone, 2-sec-Butyl Cyclo 0.16300000 2-(1- Hexanone methylpropyl)- 110. 20125-84-2 3-Octen-1-ol, Octenol 0.16000000 (3Z)- 111. 142-19-8 Heptanoic acid, Allyl Heptoate 0.16000000 2-propen-1-yl ester 112. 100-51-6 Benzenemethanol Benzyl Alcohol 0.15800000 113. 10032-15-2 Butanoic acid, 2- Hexyl-2-Methyl 0.15800000 methyl-, hexyl Butyrate ester 114. 695-06-7 2(3H)-Furanone, Gamma 0.15200000 5-ethyldihydro- Hexalactone 115. 21722-83-8 Cyclohexaneethanol, Cyclohexyl Ethyl 0.15200000 1-acetate Acetate 116. 111-79-5 2-Nonenoic acid, Methyl-2- 0.14600000 methyl ester Nonenoate 117. 16491-36-4 Butanoic acid, Cis 3 Hexenyl 0.13500000 (3Z)-3-hexen-1- Butyrate yl ester 118. 111-12-6 2-Octynoic acid, Methyl Heptine 0.12500000 methyl ester Carbonate 119. 59323-76-1 1,3-Oxathiane, Oxane 0.12300000 2-methyl-4- propyl- (2R,4S)- rel- 120. 62439-41-2 Heptanal, 6- Methoxy Melonal 0.11900000 methoxy-2,6- dimethyl- 121. 13851-11-1 Bicyclo[2,2.1]heptan- Frenchyl Acetate 0.11700000 2-ol, 1,3,3- trimethyl-, 2- acetate 122. 115-95-7 1,6-Octadien-3- Linalyl acetate 0.11600000 ol, 3,7-dimethyl-, 3-acetate 123. 18479-57-7 2-Octanol, 2,6- Tetra-Hydro 0.11500000 dimethyl- Myrcenol 124. 78-69-3 3,7- Tetra-Hydro 0.11500000 dimethyloctan-3- Linalool ol 125. 111-87-5 1-Octanol Octyl Alcohol 0.11400000 126. 71159-90-5 3-Cyclohexene- Grapefruit 0.10500000 1-methanethiol, mercaptan α,α,4-trimethyl- 127. 80-25-1 Cyclohexanemethanol, Menthanyl Acetate 0.10300000 α,α,4-trimethyl-, 1- acetate 128. 88-41-5 Cyclohexanol, 2- Verdox ™ 0.10300000 (1,1- dimethylethyl)-, 1-acetate 129. 32210-23-4 Cyclohexanol, 4- Vertenex 0.10300000 (1,1- dimethylethyl)-, 1-acetate 130. 112-44-7 Undecanal n-Undecanal 0.10200000 131. 124-19-6 Nonanal Nonanal Aldehyde 0.53200000 C-9 132. 929253-05-4 6-methoxy-2,6- 6-methoxy-2,6- 0.04020000 dimethyloctanal dimethyl octanal 133. 68039-47-4 2-propan-2- Phenethyl Isopropyl 0.24900000 yloxyethylbenzene Ether 134. 6413-10-1 ethyl 2(2- Apple Ketal 0.21900000 methyl-1,3- dioxolan-2- yl)acetate 135. 106-23-0 3,7-dimethyloct- citronellal 0.21500000 6-enal 136. 14667-55-1 Trimethyl Trimethyl Pyrazine- 1.72400000 Pyrazine-2,3,5 2,3,5 *Vapor Pressures are acquired as described in the Test Methods Section. **Origin: Same as for Table 2 hereinabove.

TABLE 4B High Volatile Fragrance Materials No. Natural oil Supplier 1. Angelica Seeds Oil Robertet 2. Basil Oil Grand Vert IFF 3. Bergamot Oil Reggio Early New Crop Capua 4. Black Pepper Oil Robertet 5. Blackcurrant Buds Absolute Robertet 6. Cardamom Guatamala Extract CO2 IFF 7. Cardamom Oil Guatemala IFF 8. Cedarleaf Oil Kerry 9. citronella oil H. Reynaud & Fils 10. Clary Sage Oil French IFF 11. Coffee Extract CO2 Firmenich 12. Cucumber Extract Firmenich 13. Cumin Oil Robertet 14. Cypress Oil IFF 15. Elemi Coeur Oil Robertet 16. Ginger oil India IFF 17. Grapefruit Zest Citrus & Allied Essences 18. It. Bergamot Oil Capua 19. Labdanum Cistus Absolute Biolandes 20. Lavandin Grosso Oil H. Reynaud & Fils 21. Lemon Oil Winter Capua 22. Green Mandarin Oil Simone Gatto 23. Nutmeg Oil Robertet 24. Oil Orange Sinensal Citrus & Allied Essences 25. Olibanum Oil Pyrogenous Firmenich 26. Pepper Black CO2 Oil Firmenich 27. Petitgrain Mandarinier Oil Misitano & Stracuzzi 28. Pink Pepper CO2 OIL Firmenich 29. Rum CO2 Oil Firmenich 30. Sichuan Pepper CO2 oil Firmenich 31. Styrax Resoid IFF 32. Tangerine Oil Robertet 33. Thym Oil IFF 34. Violet Leaves Absolute Robertet

Suppliers Biolandes, Le Sen, France Capua, Campo Calabro, Italy

Citrus & Allied Essences. New York, USA

Firmenich, Geneva, Switzerland Global Essence Inc, New Jersey, USA H. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, N.J., USA

Kerry, Co. Kerry, Ireland

Mane, Le Bar-sur-Loup, France Misitano & Stracuzzi, Messina, Italy Robertet, Grasse, France Simone Gatto, San Pierre Niceto, Italy

Exemplary high volatile fragrance materials selected from the group of Tables 4A or 4B are preferred. However, it is understood by one skilled in the art that other high volatile fragrance materials, not recited in Tables 4A or 4B, would also fall within the scope of the present invention, so long as they have a vapor pressure of greater than 0.1 Torr (0.0133 kPa) at 25° C.

Some embodiments can include a construction including a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition. The fragrance component can include a glucam modulator and at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount of greater than about 30 wt % relative to the total weight of the fragrance component. At least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount greater than about 30 wt % relative to the total weight of the fragrance component. As well as at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of less than about 30 wt %, relative to the total weight of the fragrance component.

Entrapment Materials

According to various embodiments, coating compositions, fragrance compositions, or both of the present invention can include an entrapment material at a level such that the weight ratio of the entrapment material to the coating or fragrance materials is in the range of from about 1:20 to about 20:1. In some examples, the composition may comprise an entrapment material present in the amount of from about 0.001 wt % to about 40 wt %, from about 0.1 wt % to about 25 wt %, from about 0.3 wt % to about 20 wt %, from about 0.5 wt % to about 10 wt %, or from about 0.75 wt % to about 5 wt %, relative to the total weight of the composition. The compositions disclosed herein may include from 0.001 wt % to 40%, from 0.1 wt % to 25 wt %, from 0.3 wt % to 20 wt %, from 0.5 wt % to 10 wt % or from 0.75 wt % to 5 wt %, relative to the total weight of the composition, of a cyclic oligosaccharide.

Suitable entrapment materials for use herein are selected from polymers; capsules, microcapsules and nanocapsules; liposomes, absorbents; cyclic oligosaccharides and mixtures thereof. Preferred are absorbents and cyclic oligosaccharides and mixtures thereof. Highly preferred are cyclic oligosaccharides (see PCT Publication Nos. WO2000/67721 (Procter & Gamble); and WO2000/67720 (Procter & Gamble); and U.S. Pat. No. 6,893,647 (Procter & Gamble)).

As used herein, the term “cyclic oligosaccharide” means a cyclic structure comprising six or more saccharide units. Preferred for use herein are cyclic oligosaccharides having six, seven or eight saccharide units and mixtures thereof, more preferably six or seven saccharide units and even more preferably seven saccharide units. It is common in the art to abbreviate six, seven and eight membered cyclic oligosaccharides to a, P and y respectively.

The cyclic oligosaccharide of the compositions used for the present invention may comprise any suitable saccharide or mixtures of saccharides. Examples of suitable saccharides include, but are not limited to, glucose, fructose, mannose, galactose, maltose and mixtures thereof. However, preferred for use herein are cyclic oligosaccharides of glucose. The preferred cyclic oligosaccharides for use herein are α-cyclodextrins or β-cyclodextrins, or mixtures thereof, and the most preferred cyclic oligosaccharides for use herein are β-cyclodextrins.

The cyclic oligosaccharide, or mixture of cyclic oligosaccharides, for use herein may be substituted by any suitable substituent or mixture of substituents. Herein the use of the term “mixture of substituents” means that two or more different suitable substituents can be substituted onto one cyclic oligosaccharide. The derivatives of cyclodextrins consist mainly of molecules wherein some of the OH groups have been substituted. Suitable substituents include, but are not limited to, alkyl groups; hydroxyalkyl groups; dihydroxyalkyl groups; (hydroxyalkyl)alkylenyl bridging groups such as cyclodextrin glycerol ethers; aryl groups; maltosyl groups; allyl groups; benzyl groups; alkanoyl groups; cationic cyclodextrins such as those containing 2-hydroxy-3-(dimethylamino) propyl ether; quaternary ammonium groups; anionic cyclodextrins such as carboxyalkyl groups, sulphobutylether groups, sulphate groups, and succinylates; amphoteric cyclodextrins; and mixtures thereof.

The substituents may be saturated or unsaturated, straight chain, or branched chain. Preferred substituents include saturated and straight chain alkyl groups, hydroxyalkyl groups and mixtures thereof. Preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₈ alkyl or hydroxyalkyl groups or mixtures thereof, more preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₆ alkyl or hydroxyalkyl groups or mixtures thereof, even more preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₄ alkyl or hydroxyalkyl groups and mixtures thereof. Especially preferred alkyl and hydroxyalkyl substituents are propyl, ethyl and methyl, more especially hydroxypropyl and methyl and even more preferably methyl.

Suitable cyclic oligosaccharides for use in the present invention are unsubstituted, or are substituted by only saturated straight chain alkyl, or hydroxyalkyl substituents. Therefore, preferred examples of cyclic oligosaccharides for use herein are α-cyclodextrin, β-cyclodextrin, methyl-α-cyclodextrin, methyl-β-cyclodextrin, hydroxypropyl-α-cyclodextrin and hydroxypropyl-β-cyclodextrin. Most preferred examples of cyclic oligosaccharides for use herein are methyl-α-cyclodextrin and methyl-β-cyclodextrin. These are available from Wacker-Chemie GmbH Hanns-Seidel-Platz 4, Munchen, DE under the tradename Alpha W6 M and Beta W7 M respectively.

The cyclic oligosaccharides of the compositions used for the present invention can be soluble in water, ethanol, or both water and ethanol. As used herein “soluble” means at least about 0.1 g of solute dissolves in 100 mL of solvent, at 25° C. and 1 standard atmospheric pressure (760 mmHg). The cyclic oligosaccharides for use herein have a solubility of at least about 1 g/100 mL, at 25° C. and 1 atm of pressure. In some examples, cyclic oligosaccharides are only present at levels up to their solubility limits in a given composition at room temperature. A person skilled in the art will recognize that the levels of cyclic oligosaccharides used in the present invention will also be dependent on the components of the composition and their levels, for example the solvents used or the exact fragrance oils, or combination of fragrance oils, present in the composition. Therefore, although the limits stated for the entrapment material are preferred, they are not exhaustive.

Propellants

The coating compositions, fragrance compositions, or both described herein may include a propellant. Some examples of propellants include compressed air, nitrogen, inert gases, carbon dioxide, and mixtures thereof. Propellants may also include gaseous hydrocarbons like propane, n-butane, isobutene, cyclopropane, and mixtures thereof. Halogenated hydrocarbons like 1,1-difluoroethane may also be used as propellants. Some non-limiting examples of propellants include 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, trans-1,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro-2,2-trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), monochlorodifluoromethane, and mixtures thereof. Some other propellants suitable for use include, but are not limited to, A-46 (a mixture of isobutane, butane and propane), A-31 (isobutane), A-17 (n-butane), A-108 (propane), AP70 (a mixture of propane, isobutane and n-butane), AP40 (a mixture of propane, isobutene and n-butane), AP30 (a mixture of propane, isobutane and n-butane), and 152A (1,1 difluoroethane). The propellant may have a concentration from about 15%, 25%, 30%, 32%, 34%, 35%, 36%, 38%, 40%, or 42% to about 70%, 65%, 60%, 54%, 52%, 50%, 48%, 46%, 44%, or 42% by weight of the total fill of materials stored within the container.

Antiperspirant Active

The fragrance compositions, coating compositions, or both described herein may be free of, substantially free of, or may include an antiperspirant active (e.g., any substance, mixture, or other material having antiperspirant activity). Examples of antiperspirant actives include astringent metallic salts, like the inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof. Such antiperspirant actives include, for example, the aluminum and zirconium salts, such as aluminum halides, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.

Other Ingredients

In yet another aspect, the fragrance compositions, coating compositions or both may consist essentially of the recited ingredients but may contain small amounts (not more than about 10 wt %, preferably no more than 5 wt %, or preferably no more than 2 wt % thereof, relative to the total weight of the composition) of other ingredients that do not impact on the fragrance profile, particularly the evaporation rate and release of the fragrance materials. For example, a fine fragrance composition may comprise stabilizing or antioxidant agents, UV filters or quenchers, or coloring agents, commonly used in perfumery. There are a number of other examples of additional ingredients that are suitable for inclusion in the present compositions, particularly in compositions for cosmetic use. These include, but are not limited to, alcohol denaturants such as denatonium benzoate; UV stabilizers such as benzophenone-2; antioxidants such as tocopheryl acetate; preservatives such as phenoxyethanol, benzyl alcohol, methyl paraben, and propyl paraben; dyes; pH adjusting agents such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, and sodium carbonate; deodorants and anti-microbials such as farnesol and zinc phenolsulphonate; humectants such as glycerine; oils; skin conditioning agents such as allantoin; cooling agents such as trimethyl isopropyl butanamide and menthol; silicones; solvents such as hexylene glycol; hair-hold polymers such as those described in PCT Publication No. WO94/08557 (Procter & Gamble); salts in general, such as potassium acetate and sodium chloride and mixtures thereof.

In yet another aspect, the composition of the present invention, depending on its intended use, is a mixture of fragrance materials possibly together with other ingredients such as, for example, perfume carriers. By the term “perfume carrier”, it is meant to include materials which are practically neutral from a perfumery point of view, e.g., which does not significantly alter the organoleptic properties of perfuming components. The perfume carrier may be a compatible liquid or solid fillers, diluents, and the like. The term “compatible”, as used herein, means that the components of the compositions of this invention are capable of being combined with the primary actives of the present invention, and with each other, in a manner such that there is no interaction which would substantially reduce the efficacy of the composition under ordinary use situations. The type of carrier utilized in the present invention depends on the type of product desired and may comprise, but are not limited to, solutions, aerosols, emulsions (including oil-in-water or water-in-oil), gels, and liposomes. Preferably, the carrier is a liquid and will be a solvent such as, for example, dipropyleneglycol, diethyl phthalate, isopropyl myristate, benzyl benzoate, 2-(2-ethoxyethoxy)-1-ethanol, or ethyl citrate (triethyl citrate).

In yet another aspect, the compositions for use in the present invention may take any form suitable for use, such as for perfumery or cosmetic use. These include, but are not limited to, vapor sprays, aerosols, emulsions, lotions, liquids, creams, gels, sticks, ointments, pastes, mousses, powders, granular products, substrates, cosmetics (e.g., semi-solid or liquid makeup, including foundations) and the like. In some examples, the compositions for use in the present invention take the form of a vapor spray. Compositions of the present invention can be further added as an ingredient to other compositions, preferably fine fragrance or cosmetic compositions, in which they are compatible. As such they can be used within a solid composition or applied substrates etc. Examples of products including the composition can include a fabric care product, an air care product, a home care product, a beauty care product, or a mixture thereof. Specific examples of products can include a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray. The composition can be contacted with skin, hair, or a fabric.

Article of Manufacture

The coating compositions, fragrance compositions, or both described herein may be included in an article of manufacture comprising a spray dispenser. The spray dispenser may comprise a vessel for containing the composition to be dispensed. The spray dispenser may comprise an aerosolized composition (e.g., a composition comprising a propellant) within the vessel as well. Other non-limiting examples of spray dispensers include non-aerosol dispensers (e.g., vapor sprays), manually activated dispensers, pump-spray dispensers, or any other suitable spray dispenser available in the art.

Methods of Using the Compositions

The coating compositions of the present invention, according to any embodiment, can be useful to extend the amount of time, which the fragrances in the fragrance composition are detectable. This can be a result of the modulator in the coating composition diffusing at least partially into the fragrance composition. The coating composition can be configured as a primer, a top-coat, or both.

In embodiments in which the coating composition is configured as a primer, the coating composition can be applied directly to surfaces including human or animal skin or hair, paper (fragranced paper), air in a room (air freshener or aromatherapy composition), fabric, furnishings, dishes, hard surfaces and related materials. Preferred substrates include body surfaces such as, for example, hair and skin, most preferably skin. Following application, one or more of the fragrance compositions can be applied at least partially over the coating composition. Upon or shortly after contact, the modulator or modulators in the coating composition begin to diffuse into the fragrance composition.

Alternatively, in embodiments in which the coating composition is a topcoat, the coating composition can be applied to the fragrance compositions. The fragrance compositions of the present invention according to any embodiments described herein is a useful perfuming composition, which can be advantageously used as consumer products intended to perfume any suitable substrate such as the surfaces mentioned above.

The fragrance compositions of the present invention may be used in a conventional manner for fragrancing a substrate. An effective amount of the composition, such as from about 1 μL to about 100 mL, preferably from about 10 μL to about 1,000 μL, more preferably from about 25 μL to about 500 μL, from about 50 μL to about 100 μL, from about 100 μL to about 20 mL, or combinations thereof, is applied to the suitable substrate. Alternatively, an effective amount of the composition of the present invention is less than, equal to, or greater than about 1 μL, 10 μL, 25 μL or 50 μL to about 100 μL, 500 μL, 1,000 μL, 10,000 μL, 10 mL, 20 mL, 25 mL, 30 mL, 40 mL, 50 mL, 60 mL, 70 mL, 80 mL, 90 mL, or 100 mL. The composition may be applied by hand or applied utilizing a delivery apparatus such as, for example, vaporizer or atomizer. Preferably, the composition is allowed to dry after its application to the substrate. The scope of the present invention should be considered to cover one or more distinct applications of the composition or the continuous release of a composition via a vaporizer or other type of atomizer.

Following application of the fragrance compositions, the coating composition can be at least partially applied to the fragrance composition. Upon or shortly after contact, the modulator or modulators in the coating composition begin to diffuse into the fragrance composition.

The present disclosure provides a method for imparting, intensifying, or modifying an odor on human skin or human hair, comprising applying to human skin and/or human hair the composition of the present invention. Examples of notes or characters that can be enhanced include those chosen from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.

Preferably, the fragrance profile or character of the composition of the present invention is detectable by a panel of experts or professional evaluators or individual experts or professional evaluators at later time points such as, for example, 30 mins, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 6 hours, 7 hours, 8 hours, 10 hours, and possibly all the way up to 24 hours after application of the composition to a substrate as compared to controls (e.g., those without modulators). The nature of the fragrance which is applied prior or after the drying of the coating composition is not critical for the present disclosure. The technical teaching works for all fragrances independent if they are dedicated for males or females.

In another aspect, the present invention is also directed to a method of producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a composition of the present invention.

Test Methods

The following assays set forth must be used in order that the invention described and claimed herein may be more fully understood.

Test Method 1: Determining Vapor Pressure

In order to determine the vapor pressure for the fragrance materials, go to the website https://scifinder.cas.org/scifinder/view/scifinder/scifinderExplore.jsf and follow these steps to acquire the vapor pressure.

1. Input the CAS registry number for the particular fragrance material. 2. Select the vapor pressure from the search results. 3. Record the vapor pressure (given in Torr at 25° C.).

SciFinder uses Advanced Chemistry Development (ACD/Labs) Software Version 11.02. (© 1994-2018). If the CAS number for the particular fragrance material is unknown or does not exist, you can utilize the ACD/Labs reference program to directly determine the vapor pressure. Vapor Pressure is expressed in 1 Torr, which is equal to 0.133 kilopascal (kPa).

Test Method 2: Sensory Testing

At the testing facility, samples of the compositions and the controls are applied to glass slides (50 mm width) and placed on a hot plate at 32° C. to represent skin temperature for varying durations. It is important that glass slides of samples that are to be later compared are prepared at the same time.

-   -   Assessment of fragrance EDT: Using a ‘Socorex’ regulated         pipette, apply 20 μl of the fragrance EDT product carefully to         glass slide allowing it to spread evenly.     -   Assessment when using coating solutions: Using a ‘Socorex’         regulated pipette, apply 20 μl of the primer carefully to the         glass slide allowing it to spread evenly. Wait 4 minutes for         solvent to evaporate and then add 20 μl of the fragrance EDT on         top of the primer.

Slides are presented coded with three digit numbers so that their identity is not known by the experts. The first composition evaluated by panelists is randomized. Samples and control are presented in the same tray, and panelists are able to compare both at the same moment. Panelists are selected from experienced evaluators among the industry, which have been specifically trained to differentiate fragrance samples.

Test Method 2a: Character Difference of Fragrance Test Samples Vs. Control:

At least 3 expert evaluators were selected for these experiments. Panelists are asked to give a score on a scale of 1 to 5 for changes in the perceived fragrance profile change for the test compositions versus the controls (without use of coating composition) according to the odor grading scale set out in Table herein below.

TABLE 5 Character Difference Odour Grading Scale Score Fragrance Profile change 5 Total difference in the fragrance profile from the control. 4 Large difference in fragrance profile from the control 3 Moderate fragrance profile but similar character to the control. Difference large enough for consumers to notice difference. 2 Slight fragrance profile change when compared directly with the control. 1 Frargrance profile is unchanged, i.e., no difference between the sample vs. the control.

Samples were evaluated at t=5 minutes and t=3 hours' time. The results were summarized a table indicating the mean values, standard deviation, standard error and 95% confidence intervals when variability allowed it. Statistical analysis was performed with t-test and ANOVA with R (R version 3.5.1). Furthermore, list of comments relating to fragrance character was summarized in a bar chart indicating the frequency of the same.

Test Method 2b: Quantitative Descriptive Analysis

10 female trained panelists were selected to perform evaluations, which was done in two replicates. 36 attributes were evaluated on an unlabelled continuous linear scale, where 0=not perceptible odour and 10=very strong odour. The global intensity of the fragrance was measured first, and then 35 olfactive descriptors. Samples were evaluated at t=5 minutes, t=2 hours, t=4 hours, and t=6 hours' time. The results were summarized in bar charts for the global intensity and line charts for the olfactive descriptors, with 95% confidence intervals as error bars. Three-way analysis of variance (replicate/sample/panelist−a=0.05) with interaction followed with Duncan post-hoc multiple comparison test was used as statistical data analysis.

Test Method 3: Solubility Test

Fragrance ingredient was weighed, and added progressively to 5 gr of target solution. At each step, 0.050 gr of fragrance raw material was added, and shaken vigorously during 2 minutes to form a clear aqueous solution at room temperature. When insoluble, the mixture was allowed to sit for 8 hours to solubilize. The mixture was considered soluble when not appearing cloudy and no suspended oil or particles were visible after 8 hours.

EXAMPLES

Various embodiments of the present disclosure can be better understood by reference to the following Examples which are offered by way of illustration. The present disclosure is not limited to the Examples given herein.

Example 1—Exemplary Product Compositions

Compositions I, II, III and are examples of water-based coating compositions according to the present invention. They are prepared by admixture of the components described in Table 6, in the proportions indicated.

TABLE 6 Water-based coating compositions Compositions (wt %) Ingredients CAS Number I II III Deionized Water 7732-18-5 50 to 70 70 to 80 70 to 80 Glucam P-20 61849-72-7 10 to 20 10 to 20 10 to 20 Carbopol 981 9003-01-04 0.1 to 0.3 — — Sepimax Zen — — 0.1 to 0.3 — Sodium Hydroxide 1310-73-2 0.1 to 0.3 0.1 to 0.3 — Preservatives — 0.5 to 1 0.5 to 1 0.5 to 1 Microencapsulated — 10 to 15 0.1 to 0.5 — fragrance

Preparation of water-based coating compositions was done with the following steps: in a clean and dried vessel add deionized water and glucam (phase A). Heat until 40° C. approx. and mix for 30 minutes. Reserve aside thickeners in the case of compositions I and II. In a separate vessel, add water and preservatives and heat until 70° C. approx. Let it cool down to 40° C. Start stirring (800 rpm) and sprinkle the thickeners in the case of compositions I and II, and let mix hydrate for 30 minutes. Add sodium hydroxide solution. Measure pH. For compositions I and II, add microencapsulated fragrance and correct pH if necessary.

Composition V, VI and VII are examples of ethanol-based coating compositions according to the present invention. They are prepared by admixture of the components as described in Table 24, in the proportions indicated.

TABLE 8 Ethanol-based coating compositions Compositions (wt %) Ingredients CAS Number IV V VI VII Deionized Water 7732-18-5 2 to 12 2 to 12 15 to 35 15 to 35 Alcohol denaturated 64-17-5 60 to 78 60 to 78 60 to 78 60 to 78 Glucam P-20 61849-72-7 10 to 20 10 to 20 0.1 to 7 0.1 to 7 Dermacryl 79 129702-02-9 — 0.1 to 3 — — Cavasor ® W7 128446-36-6 — — 1 to 12.5 1 to 12.5 methylated Beta-cyclodextrin

Example 2—Olfactive Test Results from Method 2a

Compositions disclosed in Tables 5-8 and different non-commercial and commercial fragrances are applied to glass slides in accordance with the protocol described in the Method Section 2a and a panel of 4 expert evaluators assess the perceived fragrance profile at initial time 0, then at 3 hours post application. Panelists are asked to score the compositions for the fidelity of the fragrance profile on a scale of 0 to 5, wherein 1 represents a no fragrance character change is detected and 5 represents a complete fragrance character change detected. The results of the panelists are then averaged and discussed below.

TABLE 9 Evaluation of character difference (1 to 5 scale) of fragrances with coating compositions versus fragrances without coating in commercial and non-commercial fragrances Coating Time No Mean CI Fragrance Type Composition Application [h] Evaluators value SD SE [90%] Diamond Female I Primer 0 4 2.25 0.50 0.25 0.80 Fragrance Diamond Female I Primer 3 4 3.75 0.50 0.25 0.80 Fragrance Diamond Female II Primer 0 4 3.50 1.00 0.50 1.59 Fragrance Diamond Female II Primer 3 4 3.50 0.58 0.29 0.92 Fragrance Diamond Female IV Primer 0 4 2.25 0.50 0.25 0.80 Fragrance Diamond Female IV Primer 3 4 2.25 0.96 0.48 1.52 Fragrance Diamond Female V Primer 0 4 3.50 0.58 0.29 0.92 Fragrance Diamond Female V Primer 3 4 3.50 0.58 0.29 0.92 Fragrance Diamond Female V Topcoat 0 4 2.75 0.50 0.25 0.80 Fragrance Diamond Female V Topcoat 3 4 3.50 0.58 0.29 0.92 Fragrance Diamond Female III Primer 0 4 3.75 0.50 0.25 0.80 Fragrance Diamond Female III Primer 3 4 2.00 0.82 0.41 1.30 Fragrance Dior Female IV Primer 0 3 2.67 0.58 0.33 1.43 J'Adore EDP Dior Female IV Primer 3 4 2.00 0.00 0.00 0.00 J'Adore EDP Dior Female V Primer 0 3 1.67 0.58 0.33 1.43 J'Adore EDP Dior Female V Primer 3 4 2.00 0.00 0.00 0.00 J'Adore EDP Dior Female V Topcoat 0 3 2.00 0.00 0.00 0.00 J'Adore EDP Dior Female V Topcoat 3 4 2.25 0.50 0.25 0.80 J'Adore EDP Lancome Female IV Primer 0 3 2.33 0.58 0.33 1.43 La Vie Est Belle EDP Lancome Female IV Primer 3 4 2.25 0.96 0.48 1.52 La Vie Est Belle EDP Lancome Female V Primer 0 3 4.00 0.00 0.00 0.00 La Vie Est Belle EDP Lancome Female V Primer 3 3 3.33 0.58 0.33 1.43 La Vie Est Belle EDP Lancome Female V Topcoat 0 3 3.67 0.58 0.33 1.43 La Vie Est Belle EDP Lancome Female V Topcoat 3 3 2.00 0.00 0.00 0.00 La Vie Est Belle EDP Boss Ma Female IV Primer 0 3 2.00 0.00 0.00 0.00 Vie EDP Boss Ma Female IV Primer 3 4 3.00 0.00 0.00 0.00 Vie EDP Boss Ma Female Vact Primer 3 4 3.50 0.58 0.29 0.92 Vie EDP Boss Ma Female V Primer 0 3 2.67 0.58 0.33 1.43 Vie EDP Boss Ma Female V Primer 3 4 3.25 0.50 0.25 0.80 Vie EDP Boss Ma Female Vact Primer 3 4 3.75 0.50 0.25 0.80 Vie EDP Boss Ma Female V Topcoat 0 3 2.33 0.58 0.33 1.43 Vie EDP Boss Ma Female V Topcoat 3 4 3.00 0.00 0.00 0.00 Vie EDP Boss Ma Female Vact Topcoat 3 4 3.00 0.00 0.00 0.00 Vie EDP Chanel Male IV Primer 0 4 2.00 0.82 0.41 1.30 Bleu EDT Chanel Male IV Primer 3 4 2.50 0.58 0.29 0.92 Bleu EDT Chanel Male V Primer 0 4 3.00 0.00 0.00 0.00 Bleu EDT Chanel Male V Primer 3 4 3.25 0.50 0.25 0.80 Bleu EDT Chanel Male V Topcoat 0 4 2.50 1.29 0.65 2.05 Bleu EDT Chanel Male V Topcoat 3 4 3.25 0.50 0.25 0.80 Bleu EDT Boss Male IV Primer 0 4 1.75 0.50 0.25 0.80 Bottled EDP Boss Male IV Primer 3 4 2.50 0.58 0.29 0.92 Bottled EDP Boss Male V Primer 0 4 3.25 0.50 0.25 0.80 Bottled EDP Boss Male V Primer 3 4 2.50 0.58 0.29 0.92 Bottled EDP Boss Male V Topcoat 0 4 3.00 0.82 0.41 1.30 Bottled EDP Boss Male V Topcoat 3 4 3.50 0.58 0.29 0.92 Bottled EDP CK One Male IV Primer 0 4 2.75 0.50 0.25 0.80 CK One Male IV Primer 3 4 3.00 0.00 0.00 0.00 CK One Male V Primer 0 4 3.75 0.96 0.48 1.52 CK One Male V Primer 3 4 2.50 1.00 0.50 1.59 CK One Male V Topcoat 0 4 3.00 0.82 0.41 1.30 CK One Male V Topcoat 3 4 2.50 0.58 0.29 0.92 act—refers to sample where cyclodextrines were activated by expiring one large breath on top of it, and immediately after evaluate by panel.

Table 9 shows the effect of coating compositions and application type (primer or topcoat) on the character of commercial and non-commercial fragrances at t=0 h and t=3 h. Overall, all of the coatings had an impact on the character at t-=3 h (95% CI: 2.72-3.01) and at t=0 h (95% CI: 2.6-2.97) and were significantly higher than score 2 (p<0.001, one-side t-test). This indicates a modification of character from the first moment of coating addition. The impact on fragrance character change over time was greater for coating compositions I and II, followed by IV, IV applied as a topcoat and V, and lastly III. These differences were significant at t=3 h (p=0.0021) analyzed with an ANOVA, indicating that the mix of modulators had a stronger effect as expected. Applying the coating composition IV as a primer rather than a topcoat drove a significantly higher character difference (3.21 and 2.9 respectively, two-sample t-test p=0.05). As it can be seen in FIG. 1, the majority of these character differences were due to coatings enhancing the fresh, fruity, floral, green, and citric notes. Other notes such as woody, aromatic and oriental notes were as well enhanced depending on the fragrances used with the coating. Similar results were observed at t=0.

TABLE 10 Evaluation of character difference (1 to 5 scale) of fragrances with coating compositions versus fragrances without coating in fragrances with a hourglass-construction Coating Time No Mean Fragrance Type Composition Application [h] Evaluators value SD SE Lacoste Male IV Primer 0 3 2.33 0.58 0.33 Essential EDT Lacoste Male IV Primer 3 3 3.00 1.00 0.58 Essential EDT Lacoste Male IV Primer 0 3 2.67 0.58 0.33 1212 Noir EDT Lacoste Male IV Primer 3 3 3.00 0.00 0.00 1212 Noir EDT

Table 10 shows the effect of coating composition applied as a primer on two commercial products with a unique fragrance composition. These fragrances were constructed with a similar content of high- and low-volatility fragrance ingredients, and a lower content of mid-volatility fragrance ingredients as per the definitions in this patent. As it can be seen from the results, over time the difference in fragrance character becomes more evident. Surprisingly, the use of the primer composition enhances aromatic, citrus and woody notes, but reduced green notes in contrast to what is observed for other constructions.

Example 3—Solubility Results

Classical perfume contain a high % of ethanol to solubilize perfume raw materials. Surprisingly, by the addition of a high amount of glucam, compensated by a removal of water, some raw materials like Ambroxan and Cedrol Crystals can be further solubilized as shown in Table 11.

In the first case, solubility increased 6.49% whereas in the second one a 57.8%. Furthermore, natural raw materials like Coffee Santos SFE could be solubilized into glucam-containing composition. This gives the opportunity to create new olfactive spaces otherwise impossible.

TABLE 11 Comparison of fragrance material solubility between a classical ethanol solution and a glucam-containing ethanol solution Max Solubility in Max Solubility in 88% Ethanol/12% 83% Ethanol/17% Fragrance Material Water solution Glucam solution Ambroxan 0.847 g 0.902 g Cerdol Crystals 0.273 g 0.431 g Coffee Santos SFE 0 g 0.054 g

The terms and expressions that have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the embodiments of the present disclosure. Thus, it should be understood that although the present disclosure has been specifically disclosed by specific embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those of ordinary skill in the art, and that such modifications and variations are considered to be within the scope of embodiments of the present disclosure.

Additional Embodiments

The following exemplary embodiments are provided, the numbering of which is not to be construed as designating levels of importance:

Embodiment 1 provides a coating composition comprising:

a carrier; and

a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 50 wt %, relative to the total weight of the composition.

Embodiment 2 provides the coating composition of Embodiment 1, where the substantially non-odorous fragrance modulator is present in the amount of from about 5 wt % to about 20 wt %.

Embodiment 3 provides the coating composition of any one of Embodiments 1 or 2, wherein the at least one substantially non-odorous fragrance modulator is chosen from glucam, methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, a cyclodextrine, an acrylate, a carboxylated acrylate/octyacrylamide copolymer, or mixtures thereof.

Embodiment 4 provides the coating composition of any one of Embodiments 1-3, wherein the at least one substantially non-odorous fragrance modulator is glucam.

Embodiment 5 provides the coating composition of any one of Embodiments 1-4, wherein the composition is substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.

Embodiment 6 provides the coating composition of any one of Embodiments 1-5, wherein the at least one substantially non-odorous fragrance modulator is chosen from:

a compound of formula (I):

wherein:

R¹ is hydrogen, alkyl, alkenyl or alkynyl;

R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)O]_(w)R⁹, wherein w is from 1 to 10, preferably 2 to 9;

R³ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]yR⁹, wherein y is

from 1 to 10 or 2 to 9;

R is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;

R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶OR⁹, —R⁶O [R⁶R⁷(R⁸)O]zR⁹,

wherein z is from 1 to 10, preferably 2 to 9;

each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and

each R⁸ and R⁹ is independently selected from hydrogen or alkyl,

a compound of formula (II):

wherein:

R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)alkynyl;

each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;

each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;

each R³ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;

each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and

R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀) alkynyl;

wherein t is 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and         -   is a saturated or unsaturated carbon-carbon bond;

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   R^(1b) is hydrogen or methyl; and         R²b is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)—(OR^(1c))_(n)   (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from         6 to 9, and m is an integer from 1 to 4;     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)   (VII)

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is an integer from 1 to 5;     -   z is an integer from 1 to 5: and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8,     -   and d is an integer from 1 to 3;     -   e is an integer from 2 to 4;     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4;     -   h is an integer from 2 to 5;     -   and R^(1f) is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)COOR^(3i)   (X).

wherein:

-   -   R^(1g) is selected from the group consisting of: (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)   (XII).

wherein:

-   -   R^(1i) is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and

Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H   (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons;

N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures;

Tricyclodecane Amide derivatives selected from the group consisting of:

-   -   the compounds of formula (XIV):

wherein:

-   -   X is selected from:

t is 1 to 8;

Y is hydrogen, or a halogen; and

each R^(1j) is independently selected from a hydrogen, or C₁-C₄ alkyl;

the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈ alkyl, cycloalkyl or cycloheteroalkyl, with the         proviso that both R^(2e) groups are not hydrogen; and         mixtures of the compounds of formulae (XII) and (XIII); and

mixtures thereof.

Embodiment 7 provides the coating composition of any one of Embodiments 1-6, wherein the coating composition comprises a plurality of modulators.

Embodiment 8 provides the coating composition of any one of Embodiments 1-7, wherein the carrier is an aqueous carrier or an organic carrier.

Embodiment 9 provides the coating composition of Embodiment 8, wherein the aqueous carrier is water.

Embodiment 10 provides the coating composition of any one of Embodiments 1-9, wherein the organic carrier is ethanol, dipropylene glycol, benzyl benzoate, diethyl phthalate, isopropyl myristate, (C₁-C₂₀)alkyl, (C₁-C₂₀)alkenyl, (C₁-C₂₀)alkynyl, (C₁-C₂₀)hydroxyl, or mixtures thereof.

Embodiment 11 provides the coating composition of any one of Embodiments 1-10, further comprising; a chelator, a thickener, an antioxidant, an emulsifier, or a combination thereof.

Embodiment 12 provides the coating composition of any one of Embodiments 1-11, further comprising at least one capsule dispersed in the composition.

Embodiment 13 provides the coating composition of Embodiment 12, wherein the at least one capsule comprises a fragrance component located therein.

Embodiment 14 provides the coating composition of any one of Embodiments 12 or 13, wherein the at least one capsule comprises a capsule wall comprising polyacrylates; polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides; epoxy resins; vinyl polymers; urea cross-linked with formaldehyde or gluteraldehyde; melamine cross-linked with formaldehyde; gelatin-polyphosphate coacervates optionally cross-linked with gluteraldehyde; gelatin-gum Arabic coacervates; cross-linked silicone fluids; polyamine reacted with polyisocyanates; acrylate monomers polymerized via free radical polymerization; silk; wool; gelatine; cellulose; proteins; and combinations thereof.

Embodiment 15 provides the coating composition of any one of Embodiments 12-14, wherein the at least one capsule is configured to degrade.

Embodiment 16 provides the coating composition of any one of Embodiments 1-15, wherein the coating composition is a primer or a top-coat.

Embodiment 17 provides a multi-component fragrance composition comprising:

the coating composition according to any one of Embodiments 1-16;

a fragrance composition in contact with the coating composition.

Embodiment 18 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount greater than 30 wt %, relative to the total weight         of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 70 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount of from about 0 wt % to about 30 wt % relative to the         total weight of the fragrance component.

Embodiment 19 provides the multi-component fragrance composition of Embodiment 18, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 20 provides the multi-component fragrance composition of any one of Embodiments 18 or 19, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 21 provides the multi-component fragrance composition of any one of Embodiments 18-20, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 22 provides the multi-component fragrance composition of any one of Embodiments 18-21, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 23 provides the multi-component fragrance composition of any one of Embodiments 18-22, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 24 provides the multi-component fragrance composition of any one of Embodiments 18-23, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 25 provides the multi-component fragrance composition of any one of Embodiments 18-24, wherein the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 26 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount of from about 0 wt % to about 30 wt % relative to         the total weight of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 70 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount greater than about 30 wt % relative to the total         weight of the fragrance component.

Embodiment 27 provides the multi-component fragrance composition of Embodiment 26, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 28 provides the multi-component fragrance composition of any one of Embodiments 26 or 2627 wherein the at least one high volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 29 provides the multi-component fragrance composition of any one of Embodiments 26-28, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 30 provides the multi-component fragrance composition of any one of Embodiments 26-29, wherein the at least one low volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 31 provides the multi-component fragrance composition of any one of Embodiments 26-30, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 32 provides the multi-component fragrance composition of any one of Embodiments 26-31, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 33 provides the multi-component fragrance composition of any one of Embodiments 26-32, wherein the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 34 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount or from about 30 wt % to about 70 wt %, relative to         the total weight of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount less than about 30         wt %, relative to the total weight of the fragrance component;         and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount of from about 0.1 wt % to about 30 wt % relative to         the total weight of the fragrance component.

Embodiment 35 provides the multi-component fragrance composition of Embodiment 34, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 36 provides the multi-component fragrance composition of any one of Embodiments 34 or 35, wherein the at least one moderate volatile fragrance material is present in an amount of from 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 37 provides the multi-component fragrance composition of any one of Embodiments 34-36, wherein the at least one high volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 38 provides the multi-component fragrance composition of any one of Embodiments 34-37, wherein the at least one low volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 39 provides the multi-component fragrance composition of any one of Embodiments 34-38, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 40 provides the multi-component fragrance composition of any one of Embodiments 34-39, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 41 provides the multi-component fragrance composition of any one of Embodiments 34-40, wherein the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 42 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C.;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C.; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C.,     -   wherein the at least one low volatile fragrance material, at         least one moderate volatile fragrance material, and at least one         high volatile fragrance material are individually present in         substantially the same amount relative to the total weight of         the fragrance component.

Embodiment 43 provides the multi-component fragrance composition of any one of Embodiment 42, wherein the composition maintains a perceived fragrance profile, particularly the characters attributable to the moderate volatile fragrance material, low volatile fragrance material, or high volatile fragrance material, to remain substantively unchanged from application up to 2 hrs, 3 hrs, 4 hrs, 5 hrs, 6 hrs or 8 hrs after application vs. a control composition that does not include the coating.

Embodiment 44 provides the multi-component fragrance composition of any one of Embodiments 42 or 43, wherein the composition maintains a perceived fragrance profile, particularly the characters attributable to the moderate volatile fragrance material, low volatile fragrance material, or high volatile fragrance material, to be substantially enhanced from application up to 2 hrs, 3 hrs, 4 hrs, 5 hrs, 6 hrs or 8 hrs after application vs. a control composition that does not include the coating.

Embodiment 45 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount of greater than about 30 wt % relative to the total         weight of the fragrance component;     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount greater than about 30 wt % relative to the total         weight of the fragrance component; and     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of less than about         30 wt %, relative to the total weight of the fragrance         component.

Embodiment 46 provides the multi-component fragrance composition of Embodiment 45, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 47 provides the multi-component fragrance composition of any one of Embodiments 45 or 46, wherein the at least one high volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 48 provides the multi-component fragrance composition of any one of Embodiments 45-47, wherein the at least one low volatile fragrance material is present in an amount of from about 30 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 49 provides the multi-component fragrance composition of any one of Embodiments 45-48, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 50 provides the multi-component fragrance composition of any one of Embodiments 45-49, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 51 provides the multi-component fragrance composition of any one of Embodiments 45-50, wherein the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 52 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount of from about 30 wt % to about 40 wt %, relative to         the total weight of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 40 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Tor (0.0133 kPa) at 25° C. present in         an amount of from about 30 wt % to about 40 wt %, relative to         the total weight of the fragrance component.

Embodiment 53 provides the multi-component fragrance composition of Embodiment 52, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 54 provides the multi-component fragrance composition of any one of Embodiments 52 or 53, wherein the at least one high volatile fragrance material is present in an amount of from 32 wt % to about 35 wt % relative to the total weight of the fragrance material.

Embodiment 55 provides the multi-component fragrance composition of any one of Embodiments 52-54, wherein the at least one moderate volatile fragrance material is present in an amount of from about 32 wt/u to about 35 wt % relative to the total weight of the fragrance material.

Embodiment 56 provides the multi-component fragrance composition of any one of Embodiments 52-55, wherein the at least one low volatile fragrance material is present in an amount of from about 32 wt % to about 35 wt % relative to the total weight of the fragrance material.

Embodiment 57 provides the multi-component fragrance composition of any one of Embodiments 52-56, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 58 provides the multi-component fragrance composition of any one of Embodiments 52-57, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 59 provides the multi-component fragrance composition of any one of Embodiments 52-58, wherein the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 60 provides the multi-component fragrance composition of Embodiment 17, wherein the fragrance composition comprises:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount less than 30 wt % relative to the total weight of         the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of higher than 45%         relative to the total weight of the fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount less than 25 wt % relative to the total weight of the         fragrance component.

Embodiment 61 provides the multi-component fragrance composition of Embodiment 60, wherein the fragrance composition further comprises at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 62 provides the multi-component fragrance composition of any one of Embodiments 60 or 61, wherein the at least one moderate volatile fragrance material is present in an amount of from 45 wt % to about 80 wt % relative to the total weight of the fragrance material.

Embodiment 63 provides the multi-component fragrance composition of any one of Embodiments 60-62, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 64 provides the multi-component fragrance composition of any one of Embodiments 60-64, wherein the at least one low volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 65 provides the multi-component fragrance composition of any one of Embodiments 60-65, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B.

Embodiment 66 provides the multi-component fragrance composition of any one of Embodiments 60-65, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B.

Embodiment 67 provides a method of using the coating composition of any one of Embodiments 1-16, the method comprising contacting the fragrance composition of any one of Embodiments 17-66 with the coating composition.

Embodiment 68 provides the method of Embodiment 67, wherein the coating composition is applied to a substrate and the fragrance component is applied to the coating composition.

Embodiment 69 provides the method of Embodiment 68, wherein the substrate comprises keratin or a fabric.

Embodiment 70 provides the method of Embodiment 69, wherein the fragrance component is applied to a substrate and the coating composition is applied to the fragrance component.

Embodiment 71 provides the method of Embodiment 70, wherein the substrate comprises keratin or a fabric.

Embodiment 72 provides the coating composition of any one of Embodiments 1-16, wherein the coating composition is free of a fragrance material.

Embodiment 73 provides the coating composition of any one of Embodiments 1-16 and 72, wherein the coating composition is substantially free of;

at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C.;

at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C.; and

at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C.

Embodiment 74 provides the coating composition of any one of Embodiments 1-16 and 72-73, wherein,

the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 4A and 4B;

the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 2A and 2B; and

the moderate volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 75 provides the coating composition of any one of Embodiments 1-16 and 72-74 wherein the composition consists essentially of substantially non-odorous materials.

Embodiment 76 provides a method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a coating composition of any one of Embodiments 17-75. 

1. A coating composition comprising: a carrier; and a substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 50 wt %, relative to the total weight of the composition.
 2. The coating composition of claim 1, where the substantially non-odorous fragrance modulator is present in the amount of from about 5 wt % to about 20 wt %.
 3. The coating composition of claim 1, wherein the at least one substantially non-odorous fragrance modulator is chosen from glucam, methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, a cyclodextrine, an acrylate, a carboxylated acrylate/octyacrylamide copolymer, or mixtures thereof.
 4. The coating composition of claim 1, wherein the at least one substantially non-odorous fragrance modulator is glucam.
 5. The coating composition of claim 1, wherein the composition is substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.
 6. The coating composition of claim 1, wherein the at least one substantially non-odorous fragrance modulator is chosen from: a compound of formula (I):

wherein: R¹ is hydrogen, alkyl, alkenyl or alkynyl; R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)O]_(w)R⁹, wherein w is from 1 to 10, preferably 2 to 9; R³ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]yR⁹, wherein y is from 1 to 10 or 2 to 9; R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)O]xR⁹, wherein x is from 1 to 10, preferably 2 to 9; R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶OR⁹, —R⁶O [R⁶R⁷(R⁸)O]zR⁹, wherein z is from 1 to 10, preferably 2 to 9; each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and each R⁸ and R⁹ is independently selected from hydrogen or alkyl, a compound of formula (II):

wherein: R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)alkynyl; each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl; each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl; each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl; each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀) alkynyl; wherein tis 5 or less, preferably 1, 2 or 3; Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures; Trimethylcyclohexane derivatives having the formula (III):

n is 0, 1 or 2; A is C═O or CH—OH; R^(1a) is hydrogen or methyl; R^(2a) is a C₂-C₁₀ hydrocarbon group; and is a saturated or unsaturated carbon-carbon bond; L-menthoxy ether derivatives having the formula (IV):

wherein: m is 0, 1 or 2; B is hydrogen or OH; and C is hydrogen or methyl; Tetra-hydronaphthalene derivatives having the formula (V):

R^(1b) is hydrogen or methyl; and R^(2b) is alkyl; 140 Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures; Ether derivatives having the formula (VI) or formula (VII): C₅H_(l)O_(m)—(OR^(1c))_(n)   (VI). C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from 6 to 9, and m is an integer from 1 to 4; n is an integer from 1 to 4; and R^(1c) is C₄-C₂₀ hydrocarbon group; and C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)   (VII). C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7 to 11, and y is an integer from 1 to 5; z is an integer from 1 to 5; and R^(1d) is C₄-C₂₀ hydrocarbon group; and Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein: C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from 6 to 8, and d is an integer from 1 to 3; e is an integer from 2 to 4; and R^(1e) is C₁-C₆ alkyl group; and

C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7 to 10, and g is an integer from 1 to 4; h is an integer from 2 to 5; and R^(1f) is C₁-C₆ alkyl group; Hydroquinone Glycoside derivatives having the formula (X): R^(1i)OCO^(R2i)COOR^(3i)   (X). R^(1g) is selected from the group consisting of: (i) pentose residue, hexose residue, aminosaccharide residue, uronic acid residue and their mixtures; (ii) methylated versions of group (i); and (iii) mixtures of groups (i) and (ii); and Propylene Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether; and their mixtures; Glyceryl Ether derivatives having the formula (XI):

R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group; Panthenol Ethyl Ether, DL-Panthenol and their mixtures; Aliphatic Dibasic Acid Diester derivatives having the formula (XII): R^(1i)OCO^(R2i)COOR^(3i)   (XII). R^(1i) is C₄-C₅ alkyl; R^(2i) is C₄ alkylene; and R^(3i) is C₄-C₅ alkyl; and Aliphatic Ether derivatives having the formula (XIII): R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H   (XIII). a and b are integers such that the sum of a and b is from 1 to 4; and R^(4i) is an aliphatic chain comprising from 8 to 18 carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures; Tricyclodecane Amide derivatives selected from the group consisting of: the compounds of formula (XIV):

wherein: X is selected from:

t is 1 to 8, each R^(1j) is independently selected from a hydrogen, or C₁-C₄ alkyl; the compounds of formula (XV):

each R^(2j) is independently selected from a hydrogen, methyl, ethyl or C₃-C₁₈ alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that both R^(2e) groups are not hydrogen; and mixtures of the compounds of formulae (XII) and (XIII); and mixtures thereof.
 7. The coating composition of claim 1, wherein the coating composition comprises a plurality of modulators.
 8. The coating composition of claim 1, wherein the carrier is an aqueous carrier or an organic carrier.
 9. The coating composition of claim 8, wherein the aqueous carrier is water.
 10. The coating composition of claim 1, wherein the organic carrier is ethanol, dipropylene glycol, benzyl benzoate, diethyl phthalate, isopropyl myristate, (C₁-C₂₀)alkyl, (C₁-C₂₀)alkenyl, (C₁-C₂₀)alkynyl, (C₁-C₂₀)hydroxyl, or mixtures thereof.
 11. The coating composition of claim 1, further comprising; a chelator, a thickener, an antioxidant, an emulsifier, or a combination thereof.
 12. The coating composition of claim 1, further comprising at least one capsule dispersed in the composition.
 13. The coating composition of claim 12, wherein the at least one capsule comprises a fragrance component located therein.
 14. The coating composition of claim 12, wherein the at least one capsule comprises a capsule wall comprising polyacrylates; polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides; epoxy resins; vinyl polymers; urea cross-linked with formaldehyde or gluteraldehyde; melamine cross-linked with formaldehyde; gelatin-polyphosphate coacervates optionally cross-linked with gluteraldehyde; gelatin-gum Arabic coacervates; cross-linked silicone fluids; polyamine reacted with polyisocyanates; acrylate monomers polymerized via free radical polymerization; silk; wool; gelatine; cellulose; proteins; and combinations thereof.
 15. The coating composition of claim 12, wherein the at least one capsule is configured to degrade.
 16. The coating composition of claim 1, wherein the coating composition is a primer or a top-coat.
 17. A multi-component fragrance composition comprising: the coating composition according to claim 1; a fragrance composition in contact with the coating composition.
 18. The multi-component fragrance composition of claim 17, wherein the fragrance composition comprises: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of: at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component; at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component; and at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0 wt % to about 30 wt % relative to the total weight of the fragrance component.
 19. The multi-component fragrance composition of claim 17, wherein the fragrance composition comprises: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of: at least one low volatile fragrance material having a vapor pressure less than 0.001 Tor (0.000133 kPa) at 25° C. present in an amount of from about 0 wt % to about 30 wt % relative to the total weight of the fragrance component; at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component; and at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount greater than about 30 wt % relative to the total weight of the fragrance component.
 20. The multi-component fragrance composition of claim 17, wherein the fragrance composition comprises: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises at least one of: at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount of greater than about 30 wt % relative to the total weight of the fragrance component; at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount greater than about 30 wt/o relative to the total weight of the fragrance component; and at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of less than about 30 wt %, relative to the total weight of the fragrance component. 